The alkylation of aminophosphanes:: A new synthesis of iminophosphoranes

被引：15

作者：

Alajarín, M ^{[1
]}

López-Leonardo, C ^{[1
]}

Llamas-Lorente, P ^{[1
]}

机构：

[1] Univ Murcia, Fac Quim, Dept Quim Organ, E-30100 Murcia, Spain

来源：

SYNLETT | 2003年 / 06期

关键词：

alkyl halides; alkylation; phosphorus; ylides; iminophosphoranes;

D O I：

10.1055/s-2003-38730

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iminophosphoranes are prepared by P-alkylation of easily available N,P,P-trisubstituted aminophosphanes with reactive alkyl halides and further deprotonation.

引用

页码：801 / 804

页数：4

共 23 条

[11]

HORNER L, 1959, LIEBIGS ANN CHEM, V627, P627

[12]

HUDSON HR, 1990, CHEM FUNCTIONAL GROU, V1, P387

[13]

Johnson A. W., 1993, YLIDES IMINES PHOSPH, P403

[14] PREPARATION AND SOME REACTIONS OF THIOACYL DIPHENYLTHIOPHOSPHINOYL AND THIOACYL DIPHENYLPHOSPHINO SULFIDES [J].

KATO, S ;

GOTO, M ;

HATTORI, R ;

NISHIWAKI, K ;

MIZUTA, M ;

ISHIDA, M .

CHEMISCHE BERICHTE-RECUEIL, 1985, 118 (04) :1668-1683

[15]

Lindner E, 2001, EUR J INORG CHEM, P2411

[16]

MOLINA P, 1994, SYNTHESIS-STUTTGART, P1197

[17]

QUIN LD, 2000, GUIDE ORGANOPHOSPHOR, P129

[18] SYNTHESIS OF N-SUBSTITUTED AMINO-PHOSPHONIUM HALIDES BY ALKYLATION REACTIONS [J].

SISLER, HH ;

SMITH, NL .

JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (11) :4733-&

[19] On new organic phosphorus bonding III Phosphine methylene derivatives and phosphinimine [J].

Staudinger, H ;

Meyer, J .

HELVETICA CHIMICA ACTA, 1919, 2 :635-646

[20]

Steiner T, 2002, ANGEW CHEM INT EDIT, V41, P48, DOI 10.1002/1521-3773(20020104)41:1<48::AID-ANIE48>3.0.CO

← 1 2 3 →