Determination of lanthanoids and yttrium in JGb2 and JR3 by inductively coupled plasma-mass spectrometry after cation-exchange pretreatment

被引:12
作者
Lee, KH
Shishido, S
Kusachi, I
Motomizu, S
机构
[1] Okayama Univ, Fac Sci, Dept Chem, Okayama 7008530, Japan
[2] Okayama Univ, Fac Educ, Dept Earth Sci, Okayama 7008530, Japan
关键词
D O I
10.2343/geochemj.34.383
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
The lanthanoids (Ln) and yttrium (Y) in rock standard samples issued from the Geological Survey of Japan (GSJ) have been determined by inductively coupled plasma-mass spectrometry (ICP-MS). Sample solutions of two igneous rocks, JGb2 and JR3, with no certified values for Ln and Y were prepared using acid digestion technique, and the Ln and Y were separated from other constituents by a cation-exchange column pretreatment. Corrections for polyatomic interference ions were made for the precise and accurate determination of Ln and Y. The analytical results for Ln and Y in JGb2 obtained by the proposed method were in good agreement with literature values, except for La (22%), obtained by other ICP-MS coupled with cation-exchange pretreatment. The discrepancy of La abundance was mainly due to the different total blank level.
引用
收藏
页码:383 / 393
页数:11
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