Ablative and Mechanical Properties of C/C-ZrC Composites Prepared by Precursor Infiltration and Pyrolysis Process

被引:53
作者
Li, Kezhi [1 ]
Xie, Jing [1 ]
Li, Hejun [1 ]
Fu, Qiangang [1 ]
机构
[1] Northwestern Polytech Univ, State Key Lab Solidificat Proc, Carbon Carbon Composites Res Ctr, Xian 710072, Peoples R China
基金
中国国家自然科学基金;
关键词
C/C composites; Ceramic-matrix composites; Ablation performance; Mechanical properties; BEHAVIORS; MICROSTRUCTURE; FABRICATION;
D O I
10.1016/j.jmst.2014.01.015
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
C/C-ZrC composites with continuous ZrC matrix were prepared by precursor infiltration and pyrolysis process using zirconium-containing polymer. Ablation properties of the composites were investigated by oxyacetylene flame with heat flux of 2380 and 4180 kW/m(2), respectively. The results showed that C/C-ZrC composites exhibited excellent ablation resistance under the heat flux of 2380 kW/m(2) for 120 s and a tree-coral-like ZrO2 protective layer formed after ablation. However, when the heat flux increased to 4180 kW/m(2), the maximum temperature of ablated surface reached 2500 degrees C and a strong degradation of ablation resistance was observed due to the weak bonding between the formed ZrO2 layer and the composites. The flexural strength of C/C-ZrC composites was 110.7 +/- 7.5 MPa. There were a large number of carbon fiber bundles pull-out, and the composites exhibited a pseudo-plastic fracture behavior.
引用
收藏
页码:77 / 82
页数:6
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