Synthesis and characterization of fibrous silica ZSM-5 for cumene hydrocracking

被引:80
作者
Firmansyah, M. L. [1 ]
Jalil, A. A. [2 ,3 ]
Triwahyono, S. [1 ,4 ]
Hamdan, H. [5 ]
Salleh, M. M. [4 ]
Ahmad, W. F. W. [4 ]
Kadja, G. T. M. [6 ]
机构
[1] Univ Teknol Malaysia, Fac Sci, Dept Chem, Utm Johor Bahru 81310, Johor, Malaysia
[2] Univ Teknol Malaysia, Inst Future Energy, Ctr Hydrogen Econ, Utm Johor Bahru 81310, Johor, Malaysia
[3] Univ Teknol Malaysia, Fac Chem & Energy Engn, Dept Chem Engn, Utm Johor Bahru 81310, Johor, Malaysia
[4] Univ Teknol Malaysia, Fac Sci, Ibnu Sina Inst Sci & Ind Res, Ctr Sustainable Nanomat, Utm Johor Bahru 81310, Johor, Malaysia
[5] Univ Teknol Malaysia, UTM Razak Sch Engn & Adv Technol, Utm Kuala Lumpur 54100, Malaysia
[6] Inst Teknol Bandung, Fac Math & Nat Sci, Dept Inorgan & Phys Chem, Bandung 40132, Indonesia
关键词
CATALYTIC PERFORMANCE; DEHYDROGENATION; ZEOLITE; NANOPARTICLES; ETHYLBENZENE; CRACKING;
D O I
10.1039/c6cy00106h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Inspired by the high accessibility and low diffusion limitations of fibrous silica nanoparticles (KCC-1), fibrous silica ZSM-5 (FZSM-5) was engineered using a microemulsion system. The spherical FZSM-5 with a dendrimeric silica fiber possessed a high surface area (554 m(2)), a wide pore diameter (2-20 nm), abundant strong acid sites and high catalytic activity towards cumene hydrocracking.
引用
收藏
页码:5178 / 5182
页数:5
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