Synthesis and structure of a cationic platinum borylene complex

被引：66
|
作者：
Braunschweig, Holger [1 ]
Radacki, Krzysztof [1 ]
Uttinger, Katharina [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 21期
关键词：
boron; borylene ligands; platinum; structure elucidation; transition-metal complexes;
D O I：
10.1002/anie.200605191
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Making a B line: The boryl complex trans-[(Cy3P) 2Pt(Br){B(Mes)Br}] was synthesized and converted into the first two-coordinate borylene complex of platinum, trans-[(Cy3P) 2Pt(Br)(BMes)]+ (see picture), in which the boron atom is linearly coordinated. The bonding situation was analyzed by theoretical calculations and structural methods. Mes = 2,4,6-Me3C 6H2. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：3979 / 3982
页数：4
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