Step edge structures on the anatase TiO2 (001) surface studied by atomic-resolution TEM and STM

被引：14
作者：
Ek, M. [1 ]
Beinik, I. [2 ]
Bruix, A. [2 ]
Wendt, S. [2 ]
Lauritsen, J. V. [2 ]
Helveg, S. [1 ]
机构：
[1] Haldor Topsoe Res Labs, Haldor Topsoes Allee 1, DK-2800 Lyngby, Denmark
[2] Aarhus Univ, Dept Phys & Astron, Interdisciplinary Nanosci Ctr iNANO, DK-800 Aarhus C, Denmark
来源：
FARADAY DISCUSSIONS | 2018年 / 208卷
关键词：
ELECTRON-MICROSCOPY; CATALYSTS; DEFECTS; SCIENCE; ENERGY; OXIDE;
D O I：
10.1039/c7fd00222j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Low-coordinate surface sites, such as those present on high-index step edges, often exhibit chemical reactivity that markedly differs from more close-packed facets. To understand the site-specific reactivity, insight into the three-dimensional atomic arrangement of step edges is needed. Here, we employ atomic-resolution transmission electron microscopy (TEM) of nanoparticles in combination with scanning tunneling microscopy (STM) of a single crystal surface to uncover the structure of prevalent step edges on the anatase TiO2 (001) surface.
引用
收藏
页码：325 / 338
页数：14
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