Step edge structures on the anatase TiO2 (001) surface studied by atomic-resolution TEM and STM

被引：14

作者：

Ek, M. ^{[1
]}

Beinik, I. ^{[2
]}

Bruix, A. ^{[2
]}

Wendt, S. ^{[2
]}

Lauritsen, J. V. ^{[2
]}

Helveg, S. ^{[1
]}

机构：

[1] Haldor Topsoe Res Labs, Haldor Topsoes Allee 1, DK-2800 Lyngby, Denmark

[2] Aarhus Univ, Dept Phys & Astron, Interdisciplinary Nanosci Ctr iNANO, DK-800 Aarhus C, Denmark

来源：

FARADAY DISCUSSIONS | 2018年 / 208卷

关键词：

ELECTRON-MICROSCOPY; CATALYSTS; DEFECTS; SCIENCE; ENERGY; OXIDE;

D O I：

10.1039/c7fd00222j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Low-coordinate surface sites, such as those present on high-index step edges, often exhibit chemical reactivity that markedly differs from more close-packed facets. To understand the site-specific reactivity, insight into the three-dimensional atomic arrangement of step edges is needed. Here, we employ atomic-resolution transmission electron microscopy (TEM) of nanoparticles in combination with scanning tunneling microscopy (STM) of a single crystal surface to uncover the structure of prevalent step edges on the anatase TiO2 (001) surface.

引用

页码：325 / 338

页数：14

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