Synthesis, Crystal Structures, and Catalytic Oxidation Properties of Oxidovanadium(V) Complexes with Hydrazone and Hydroxamate Ligands

被引：0

作者：

Yang, Kui-Hua ^{[1
]}

机构：

[1] Mianyang Normal Univ, Sch Chem & Chem Engn, Mianyang 621000, Peoples R China

来源：

ACTA CHIMICA SLOVENICA | 2014年 / 61卷 / 03期

关键词：

Hydrazone; Oxidovanadium; Crystal structure; Catalytic property; VANADIUM COMPLEXES; OXOVANADIUM(V); EPOXIDATION; REACTIVITY; BEHAVIOR;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new oxidovanadium(V) complexes with hydrazone ligands and hydroxamate ligands were synthesized and characterized by IR and H-1 NMR spectroscopy, elemental analysis and single crystal X-ray diffraction. The coordination sphere of each V atom is octahedral, constructed from three donor atoms of the hydrazone ligand, two donor atoms of the hydroxamate ligand, and one oxido oxygen. Both complexes show effective catalytic oxidation properties for the oxidation of cyclohexene, cyclopentene and benzyl alcohol using H2O2 as primary oxidant.

引用

页码：629 / 636

页数：8

共 32 条

[1] New organoplatinum (IV) complex with quaterpyridine ligand: Synthesis, structure and its catalytic activity in the hydrosilylation of styrene and terminal alkynes [J].

Adamski, Ariel ;

Kubicki, Maciej ;

Pawluc, Piotr ;

Grabarkiewicz, Tomasz ;

Patroniak, Violetta .

CATALYSIS COMMUNICATIONS, 2013, 42 :79-83

[2] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].

ALLEN, FH ;

KENNARD, O ;

WATSON, DG ;

BRAMMER, L ;

ORPEN, AG ;

TAYLOR, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19

[3] Synthesis and antileishmanial activity of novel pyridinium-hydrazone derivatives [J].

Alptuzun, Vildan ;

Cakiroglu, Gokcer ;

Limoncu, M. Emin ;

Erac, Bayri ;

Hosgor-Limoncu, Mine ;

Erciyas, Ercin .

JOURNAL OF ENZYME INHIBITION AND MEDICINAL CHEMISTRY, 2013, 28 (05) :960-967

[4] Synthesis, X-ray structure, DFT studies, and catalytic activity of a vanadium(V) complex containing a tridentate Schiff base [J].

Amini, Mojtaba ;

Arab, Ali ;

Soleyman, Rouhollah ;

Ellern, Arkady ;

Woo, L. Keith .

JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (21) :3770-3781

[5]

[Anonymous], 2007, SMART VERS 5 625 SAI

[6] VANADIUM COMPLEXES WITH TRIDENTATE DIACIDIC LIGANDS - THE CRYSTAL-STRUCTURES OF BIS[ACETYLACETONATO-THIOBENZOYLHYDRAZONATO(2-)]VANADIUM(IV), METHOXO-OXO-[SALICYLALDEHYD-THIOBENZOYLHYDRAZONATO(2-)]VANADIUM(V), AND METHOXO-OXO-[SALICYLALDEHYDBENZOYLHYDRAZONATO(2-)]METHANOL VANADIUM(V) [J].

BANSSE, W ;

LUDWIG, E ;

UHLEMANN, E ;

WELLER, F ;

DEHNICKE, K ;

HERRMANN, W .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 613 (07) :36-44

[7] Helical Oxidovanadium(IV) Salen-Type Complexes: Synthesis, Characterisation and Catalytic Behaviour [J].

Barman, Sanmitra ;

Patil, Smita ;

Desper, John ;

Aikens, Christine M. ;

Levy, Christopher J. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 2013 (33) :5708-5717

[8] Synthesis, crystal structure, spectroscopic study, and magnetic behavior of the first dinuclear Mn(II) complex of hydrazone-based ligand-containing dicyanamide bridging groups [J].

Bikas, Rahman ;

Hosseini-Monfared, Hassan ;

Sieron, Leslaw ;

Gutierrez, Angel .

JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (22) :4023-4031

[9] Synthesis and Structural Characterization of Molybdenum(VI) and Iron(II) Coordination Compounds with S-Alkyl-N-methyl-S-(2-pyridyl)sulfoximines and Catalytic Epoxidation Activity of the Molybdenum Complexes [J].

Brussaard, Yvonne ;

Olbrich, Falk ;

Schaumann, Ernst .

INORGANIC CHEMISTRY, 2013, 52 (22) :13160-13166

[10] Syntheses and characterization of four novel monooxovanadium(V) hydrazone complexes with hydroxamate or alkoxide ligand [J].

Gao, S ;

Weng, ZQ ;

Liu, SX .

POLYHEDRON, 1998, 17 (20) :3595-3606

← 1 2 3 4 →