2-(4-Bromophenyl)-1-(methylsulfanyl)naphtho[2,1-b]furan

被引:1
|
作者
Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
机构
[1] Pukyong Natl Univ, Dept Chem, Pusan 608737, South Korea
[2] Dong Eui Univ, Dept Chem, Pusan 614714, South Korea
关键词
D O I
10.1107/S1600536807022180
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C19H13BrOS, was synthesized by the Lewis acid-catalyzed reaction of 2-naphthol with 40-bromo-2chloro- 2-(methylsulfanyl) acetophenone. The methyl group lies above the naphthofuran ring system and the benzene ring is rotated out of the naphthofuran plane with a dihedral angle of 42.29 (8)degrees. The crystal structure is stabilized by aromatic pi-pi stacking between the furan and benzene rings, C-H center dot center dot center dot O and C-H center dot center dot center dot Br hydrogen bonds, and a Br center dot center dot center dot Br interaction.
引用
收藏
页码:O2895 / U2375
页数:10
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