An unusual binodal (6,8)-connected 3D supramolecular network with twofold self-penetration

被引：0

作者：

Zhan CaiHong ^{[1
]}

Cai WenXuan ^{[1
]}

Feng YunLong ^{[1
]}

He YinHua ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China

来源：

SCIENCE CHINA-CHEMISTRY | 2010年 / 53卷 / 06期

关键词：

5-carboxyl-1-carboxymethyl-2-oxidopyridinium; supramolecule; luminescence property; crystal structure; self-penetration network; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CHEMISTRY; DESIGN; PHOTOLUMINESCENT; TOPOLOGIES; CLUSTERS;

D O I：

10.1007/s11426-010-3178-x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dicarboxylate ligand, 5-carboxyl-1-carboxymethyl-2-oxidopyridinium (H2L), was utilized to form four complexes with the general formula [M(HL)(2)(H2O)] center dot 2H(2)O, M = Cu-II (1), Zn-II (2), Mn-II (3), Cd-II (4). The crystals were isomorphous, belonging to the monoclinic C2/c space group. They were constructed from 1D chains and further linked by hydrogen bonds into a novel binodal (6,8)-connected 3D supramolecular network with twofold self-penetration. Photoluminescence studies revealed that complexes 2-4 displayed intense structure-related fluorescent emission bands.

引用

页码：1261 / 1265

页数：5

共 27 条

[1] An unusual binodal (6,8)-connected 3D supramolecular network with twofold self-penetration
ZHAN CaiHong
Science China(Chemistry), 2010, (06) : 1261 - 1265
[2] An unusual binodal (6,8)-connected 3D supramolecular network with twofold self-penetration
CaiHong Zhan
WenXuan Cai
YunLong Feng
YinHua He
Science China Chemistry, 2010, 53 : 1261 - 1265
[3] An Unusual Binodal (4,12)-Connected 3D Supramolecular Network Based on [Mn4(OH)2(H2O)2]6+ Subunits
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