Synthesis and structures of cationic μ-diborolyl triple-decker complexes [CpCo(1,3-C3B2Me5)M(C5R5)]+ (M = Rh or Ir)

被引：2

作者：

Romanov, A. S. ^{[1
,2
]}

Muratov, D. V. ^{[1
]}

Petrovskii, P. V. ^{[1
]}

Antipin, M. Yu ^{[1
,2
]}

Siebert, W. ^{[3
]}

Kudinov, A. R. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

[2] New Mexico Highlands Univ, Dept Nat Sci, Las Vegas, NM 87701 USA

[3] Univ Heidelberg, Dept Inorgan Chem, D-69120 Heidelberg, Germany

来源：

RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 03期

关键词：

boron-containing heterocycles; iridium; cobalt; rhodium; sandwich compounds; triple-decker complexes; CYCLOPENTADIENYL LIGANDS; ARENE COMPLEXES; HYDROGEN-BONDS; BOROLE LIGAND; METALLACARBORANE; CRYSTAL; METALS;

D O I：

10.1007/s11172-009-0061-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cationic triple-decker complexes [CpCo(1,3-C3B2Me5)M(C5R5)](+) (M = Rh (2), Ir (3), R = H (a), Me (b)) with the bridging diborolyl ligand were synthesized by the reaction of the sandwich anion [CpCo(1,3-C3B2Me5)](-) (1) with the halide complexes [CpMI2](2) or [Cp*MCl2](2) (Cp* = C5Me5). The structures of [2b]PF6 and [3b]PF6 were established by X-ray diffraction. The nature of the metal-diborolyl bond in these complexes was analyzed using the energy decomposition scheme.

引用

页码：594 / 599

页数：6

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