Flame propagation behaviors and influential factors of TiH2 dust explosions at a constant pressure

被引:44
作者
Cheng, Yang-fan [1 ,2 ]
Meng, Xiang-rui [1 ]
Ma, Hong-hao [2 ,3 ]
Liu, Shang-hao [1 ]
Wang, Quan [1 ]
Shu, Chi-min [1 ,4 ]
Shen, Zhao-wu [2 ]
Liu, Wen-jin [1 ]
Song, Shi-xiang [1 ]
Hua, Fang [1 ]
机构
[1] Anhui Univ Sci & Technol, Sch Chem Engn, Huainan 232001, Peoples R China
[2] Univ Sci & Technol China, CAS Key Lab Mech Behav & Design Mat, Hefei 230027, Anhui, Peoples R China
[3] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
[4] Natl Yunlin Univ Sci & Technol, Proc Safety & Disaster Prevent Lab, Touliu 64002, Yunlin, Taiwan
基金
中国国家自然科学基金;
关键词
Hydrogen storage alloy; Dust cloud; TiH2; Freely-propagating flame; Burning velocity; HYDROGEN-STORAGE; PARTICLE-COMBUSTION; ALUMINUM DUST; QUENCHING DISTANCE; TITANIUM HYDRIDE; AIR; CLOUDS; MIXTURES; GAS; POWDER;
D O I
10.1016/j.ijhydene.2018.06.145
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The flame propagation through TiH2 dust cloud at near constant pressure condition is studied in a series of experiments using an apparatus with transparent latex balloons. The influential factors for the combustion performance of TiH2 dust cloud, including dust concentration, particle size, scale of isobaric space and oxygen content are investigated. Results show that the burning velocity increases with dust concentration in the fuel-lean mixtures, and then plateaus after crossing the stoichiometric condition, while the trend of flame speed changing with dust concentration varies for different mean particle sizes (D-50) of 48 and 106 mu m. The flame propagation speed of dust cloud is positively correlated to the isobaric space scale and oxygen content. The burning mechanism of TiH2 dust is thought to be mainly controlled by diffusion regime, the appearance of hydrogen gas accelerates the combustion rate of TiH2 particles and also makes the TiH2 dust changed from a discrete media to a continuum, which may account for the phenomenon that the flame speed in dust cloud of TiH2 is larger than that of Ti at the same concentration no matter in air or oxygen atmosphere. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:16355 / 16363
页数:9
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