Octamethylferrocenylethynyl units as peripheral groups in rigid, π-conjugated molecular architectures

被引：25

作者：

Jutzi, P ^{[1
]}

Kleinebekel, B ^{[1
]}

机构：

[1] Univ Bielefeld, Fak Chem, D-33615 Bielefeld, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 545卷

关键词：

ferrocene; alkyne; multimetallic assembly; electrochemistry;

D O I：

10.1016/S0022-328X(97)00360-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and full characterization of octamethylethynylferrocene 2 is described. Additionally, the reaction of 2 with copper(II) acetate, 1,4-diiodobenzene and 1,3,5-triiodobenzene to give 1.4-bis(octamethylferrocenyl)butadiyne 3, 1,4-bis(octamethylferroceny lethynyl)benzene 4 and 1,3,5-tris(octamethyferrocenyllethyny)be 5 is presented. As a result of electrochemical investigations of 2-5 only 3 shows two one-electron oxidations with a peak-separation of 150 mV. (C) 1997 Elsevier Science S.A.

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收藏

页码：573 / 576

页数：4

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