Effect of O2 contamination on carbon steel pseudo-passive scales in CO2 aqueous solutions

被引:7
作者
Basilico, Edoardo [1 ,2 ]
Marcelin, Sabrina [2 ]
Mingant, Remy [1 ]
Kittel, Jean [1 ]
Fregonese, Marion [2 ]
Barker, Richard [3 ]
Owen, Joshua [3 ]
Neville, Anne [3 ]
Ropital, Francois [1 ,2 ]
机构
[1] IFP Energies Nouvelles, BP 3, F-69360 Solaize, France
[2] Univ Claude Bernard Lyon 1, Univ Lyon, UMR5510, MATEIS,INSA Lyon,CNRS, F-69621 Villeurbanne, France
[3] Univ Leeds, Sch Mech Engn, Inst Funct Surfaces, Leeds LS2 9JT, W Yorkshire, England
关键词
Oxygen contamination; Pseudo-passivation; CO2; corrosion; Corrosion product layer; Siderite; Pitting; MILD-STEEL; CORROSION BEHAVIOR; DIOXIDE; IMPURITIES; EVOLUTION; MODEL; FILM; OIL;
D O I
10.1016/j.corsci.2022.110388
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Waters containing CO2 can lead to the formation of a "pseudo passive " protective corrosion product layer on carbon steel, however an oxygen contamination can significantly alter the corrosion behavior. The carbon steel API 5 L X65 specimens were tested in a CO2 saturated solution with small concentrations of O-2 (90-270 ppb). Electrochemical techniques, Raman spectroscopy and SEM were used for determining the corrosion product layer properties. Oxygen contamination induces pits that result in a significant increase and instability of the open circuit potential. Removing the oxygen contamination, stops pits propagation and the carbon steel surface regains its "pseudo-passive " behavior.
引用
收藏
页数:11
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