The first μ6-peroxide transition-metal complex:: [Ni8(L)12(O2)]2+

被引：19

作者：

Brown, EJ ^{[1
]}

Duhme-Klair, AK ^{[1
]}

Elliott, MI ^{[1
]}

Thomas-Oates, JE ^{[1
]}

Timmins, PL ^{[1
]}

Walton, PH ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 09期

关键词：

cluster compounds; coordination modes; hydroxypyridinones; nickel; peroxides;

D O I：

10.1002/anie.200461892

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Caged peroxide: An octanuclear nickel complex, which exhibits peroxide in an unprecedented μ6-(η1)3 coordination mode, was prepared (see structure: only the Ni8 unit with the central peroxo ligand and the bridging oxygen atoms is shown; green Ni, red O). This mode of binding finally completes the series of symmetrical μn- (η1)n/2 peroxide binding modes in complexes. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1392 / 1395

页数：4

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