A Comparison of the Structure, Synthesis, and Properties of Insensitive Energetic Compounds

被引:113
作者
Pagoria, Philip [1 ]
机构
[1] Lawrence Livermore Natl Lab, 7000 East Ave,L-282, Livermore, CA 94550 USA
关键词
Insensitive energetic compounds; Explosives; TATB; Nitrocompounds; Energetic heterocycles; VICARIOUS NUCLEOPHILIC-SUBSTITUTION; IMPACT SENSITIVITY; POLYNITRO COMPOUNDS; CRYSTAL-STRUCTURE; PERFORMANCE; EXPLOSIVES; REACTIVITY; DERIVATIVES; PYRAZOLES;
D O I
10.1002/prep.201600032
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The continued interest in improving the safety of munitions towards unintentional insults has led to a significant amount of research in the synthesis of new insensitive energetic compounds. This paper discusses various approaches to the synthesis of insensitive energetic compounds, theoretical modeling and correlations of structural properties that contribute to reducing the sensitivity of energetic compounds, and how synthetic chemists integrate theoretical predictions into the design and synthesis of new insensitive energetic compounds.
引用
收藏
页码:452 / 469
页数:18
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