Metal-Free Phosphine Oxide Reductions Catalyzed by B(C6F5)3 and Electrophilic Fluorophosphonium Cations

被引：70
作者：
Mehta, Meera [1 ]
de la Arada, Isaac Garcia [1 ]
Perez, Manuel [1 ]
Porwal, Digvijay [2 ]
Oestreich, Martin [2 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada
[2] Tech Univ Berlin, Inst Chem, Str 17 Juni 115, D-10623 Berlin, Germany
来源：
ORGANOMETALLICS | 2016年 / 35卷 / 07期
基金：
加拿大自然科学与工程研究理事会;
关键词：
TERTIARY; HYDROSILYLATION; TRIPHENYLPHOSPHINE; HYDROSILATION; SECONDARY; HYDROGENATION; SELECTIVITY; CONVERSION; MECHANISM; REAGENT;
D O I：
10.1021/acs.organomet.6b00158
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrosilylation/reduction of tertiary and secondary phosphine oxides to phosphines is catalyzed by B(C6F5)(3) or electrophilic fluorophosphonium cations (EPCs). B(C6F5)(3) is an effective catalyst for phosphine oxide reduction using (EtO)(3)SiH, PhSiH3, and Ph2SiH2 at elevated temperature (105 degrees C), while EPCs effect the same reduction at significantly lower temperature with PhSiH3 as reducing agent, allowing for good functional-group tolerance.
引用
收藏
页码：1030 / 1035
页数：6
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