Deformation mechanism of iPP under uniaxial stretching over a wide temperature range: An in-situ synchrotron radiation SAXS/WAXS study

被引：57

作者：

Chen, Xiaowei ^{[1
]}

Lv, Fei ^{[1
]}

Su, Fengmei ^{[1
]}

Ji, Youxin ^{[1
]}

Meng, Lingpu ^{[1
]}

Wan, Caixia ^{[1
]}

Lin, Yuanfei ^{[1
]}

Li, Xueyu ^{[1
]}

Li, Liangbin ^{[1
]}

机构：

[1] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, CAS Key Lab Soft Matter Chem, Hefei 230026, Peoples R China

来源：

POLYMER | 2017年 / 118卷

关键词：

Polypropylene; Uniaxial stretching; Film processing; Morphology diagram; X-RAY-SCATTERING; MICROPOROUS MEMBRANE FORMATION; HIGH-DENSITY POLYETHYLENE; ISOTACTIC POLYPROPYLENE; PLASTIC-DEFORMATION; INDUCED CRYSTALLIZATION; ALPHA-RELAXATION; SHISH-KEBABS; NECK REGION; MORPHOLOGY;

D O I：

10.1016/j.polymer.2017.04.054

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

With a combination of homemade temperature jump extension apparatus and in-situ synchrotron radiation small and wide angle X-ray scattering (SR-SAXS and SR-WAXS) measurements, uniaxial stretching experiments of polypropylene films at 50 degrees C-150 degrees C are carried out to obtain the structure evolution routes. Three distinct features of the structure evolution are observed in temperature space, which can be described with three different deformation models, namely amorphization, crystalline block slip and melt recrystallization, respectively. Also, a refined morphology diagram in strain temperature space is given to specify the morphology under two dimensional stretching parameter space. This work supplies a guidance for selecting processing conditions to obtain optimal structures after uniaxial stretching in industry. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：12 / 21

页数：10

共 64 条

[1]

Alexander LE., 1969, X-ray Diffraction Methods in Polymer Scienc

[2]

[Anonymous], 2003, MACROMOLECULES, V36, P4689

[3] Toughenability of polymers [J].