Synthesis of Highly Sensitive Fluorescent Probe Based on Tetrasubstituted Imidazole and Its Application for Selective Detection of Ag+ Ion in Aqueous Media

被引：11

作者：

Mi Zhiming ^{[1
]}

Chen Yao ^{[1
]}

Chen Xiaodong ^{[1
]}

Yan Liuqing ^{[1
]}

Gu Qiang ^{[1
]}

Zhang Hanqi ^{[1
]}

Chen Chunhai ^{[1
]}

Zhang Yumin ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, Changchun 130012, Jilin, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2018年 / 34卷 / 03期

关键词：

Fluorescent probe; Imidazole; Ag+ ion; Microwave irradiation; LIVING CELLS; CONJUGATED POLYMERS; SILVER(I) IONS; CHEMOSENSOR; COMPLEXES; SENSORS; CU2+;

D O I：

10.1007/s40242-018-7426-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A small molecule fluorescent probe, 4-[2-(4-chlorophenyl)-4,5-diphenyl-1H-imidazol-1-yl]aniline(L) for detecting Ag+ ion was gently synthesized via one-pot multi-component reaction catalyzed by H-3[PW12O40] under solvent-free microwave irradiation. When the concentration of Ag+ ion changed from 0 to 8.0 x10(-6) mol/L in the solution of H2O/CH3OH(19:1, volume ratio), the fluorescence emission spectrum was blue-shifted and accompanied by a gradual increase in fluorescence intensity with a low detection limit of 3.0x10(-11) mol/L. Moreover, UV-Vis absorption titration experiment demonstrated a 1:1 stoichiometric ratio and an association constant of (9.95 +/- 0.44)x10(5) L/mol between probe L and Ag+ ion, and thus their complexation mechanism was also proposed and verified. More importantly, this fluorescent probe was remarkably specific for Ag+ ion under the interference of other metal ions and exhibited a wide pH application range of 4.0-8.0. Additionally, preliminary application of this probe was also carried out and satisfactory results were shown.

引用

页码：369 / 374

页数：6

共 34 条

[1] The two spin states of an end-on copper(II)-superoxide mimic [J].

Askari, Mohammad S. ;

Girard, Brigitte ;

Murugesu, Muralee ;

Ottenwaelder, Xavier .

CHEMICAL COMMUNICATIONS, 2011, 47 (28) :8055-8057

[2] Microwave-Assisted Synthesis of Colloidal Inorganic Nanocrystals [J].

Baghbanzadeh, Mostafa ;

Carbone, Luigi ;

Cozzoli, P. Davide ;

Kappe, C. Oliver .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (48) :11312-11359

[3] Conjugated polymers containing a 2,2′-biimidazole moiety-a novel fluorescent sensing platform [J].

Bao, Yinyin ;

Li, Qianbiao ;

Liu, Bin ;

Du, Fanfan ;

Tian, Jiao ;

Wang, Hu ;

Wang, Yanxue ;

Bai, Ruke .

CHEMICAL COMMUNICATIONS, 2012, 48 (01) :118-120

[4] A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].

BENESI, HA ;

HILDEBRAND, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2703-2707

[5] The roles of imidazole ligands in coordination supramolecular systems [J].

Chen, Shui-Sheng .

CRYSTENGCOMM, 2016, 18 (35) :6543-6565

[6] Efficient synthesis of 1-R1-2-R-4,5-di(furan-2-yl)-1H-imidazoles and their luminescence properties [J].

Chen, Yao ;

Gu, Qiang ;

Li, Baozhi ;

Chen, Qiu ;

Chen, Xiaodong ;

Zhang, Yumin ;

Liu, Jinxin .

COMPTES RENDUS CHIMIE, 2013, 16 (12) :1103-1110

[7] Metallo-homopolymer and metallo-copolymers containing light-emitting poly (fluorene/ethynylene/(terpyridyl)zinc (II)) backbones and 1,3,4-oxadiazole (OXD) pendants [J].

Chen, Yi-Yu ;

Lin, Hong-Cheu .

POLYMER, 2007, 48 (18) :5268-5278

[8] Blue emission of a soluble poly(p-phenylene) with a cross-conjugated bisimidazole-based chromophore [J].

Dierschke, Frank ;

Muellen, Klaus .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2007, 208 (01) :37-43

[9] Turn-on fluorescent chemosensor for determination of lutetium ion [J].

Faridbod, F. ;

Sedaghat, M. ;

Hosseini, M. ;

Ganjali, M. R. ;

Khoobi, M. ;

Shafiee, A. ;

Norouzi, P. .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 137 :1231-1234

[10] Optical sensors based on hybrid aptamer/conjugated polymer complexes [J].

Ho, HA ;

Leclerc, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (05) :1384-1387

← 1 2 3 4 →