Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes

被引：1181

作者：

Alvarez, Andrea ^{[1
]}

Bansode, Atul ^{[1
]}

Urakawa, Atsushi ^{[1
]}

Bavykina, Anastasiya V. ^{[2
]}

Wezendonk, Tim A. ^{[2
]}

Makkee, Michiel ^{[2
]}

Gascon, Jorge ^{[2
]}

Kapteijn, Freek ^{[2
]}

机构：

[1] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Avinguda dels Paisos Catalans 16, Tarragona 43007, Spain

[2] Delft Univ Technol, Chem Engn Dept, Catalysis Engn, Van Maasweg 9, NL-2629 HZ Delft, Netherlands

来源：

CHEMICAL REVIEWS | 2017年 / 117卷 / 14期

关键词：

DIMETHYL ETHER SYNTHESIS; CARBON-DIOXIDE HYDROGENATION; IMMOBILIZED RUTHENIUM CATALYST; TRANSITION-METAL-COMPLEXES; GAS-SHIFT REACTION; ONE-STEP SYNTHESIS; FORMIC-ACID; HOMOGENEOUS CATALYSIS; CU/ZNO/AL2O3; CATALYSTS; ORGANIC FRAMEWORK;

D O I：

10.1021/acs.chemrev.6b00816

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The recent advances in the development of heterogeneous catalysts and processes for the direct hydrogenation of CO2 to formate/foimic acid, methanol, and dimethyl ether are thoroughly reviewed, with special emphasis on thermodynamics and catalyst design considerations. After introducing the main motivation for the development of such processes, we first summarize the most important aspects of CO2 capture and green routes to produce H-2. Once the scene in terms of feedstocks is introduced, we carefully summarize the state of the art in the development of heterogeneous catalysts for these important hydrogenation reactions. Finally, in an attempt to give an order of magnitude regarding CO2 valorization, we critically assess economical aspects of the production of methanol and DME and outline future research and development directions.

引用

页码：9804 / 9838

页数：35

共 276 条

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