Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc(II) N,N-dimethylformamide monosolvate

被引：3
|
作者：
Muslim, Mohd [1 ]
Faizi, Md Serajul Haque [2 ]
Ali, Arif [1 ]
Afzal, Mohd [3 ]
Ahmad, Musheer [1 ]
Dege, Necmi [4 ]
Mashrai, Ashraf [5 ]
机构：
[1] Aligarh Muslim Univ, Fac Engn & Technol, Dept Appl Chem, ZHCET, Aligarh 202002, Uttar Pradesh, India
[2] BRA Bihar Univ, Langat Singh Coll, PG Dept Chem, Muzaffarpur 842001, Bihar, India
[3] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
[4] Ondokuz Mayis Univ, Arts & Sci Fac, Dept Phys, TR-55139 Atakum, Samsun, Turkey
[5] Univ Sci & Technol, Dept Pharm, Ibb Branch, Ibb, Yemen
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2021年 / 77卷
关键词：
crystal structure; benzimidazole; aniline; bidentate ligand; heterocyclic; zinc(II) complex; LONE PAIR-PI; BIOLOGICAL EVALUATION; DERIVATIVES;
D O I：
10.1107/S2056989021003649
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [ZnCl2(C13H11N3)]center dot C3H7NO, crystallized in the monoclinic crystal system in space group P2(1)/n. The asymmetric unit contains one neutral complex molecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with dimethylformamide monosolvate. The ligand has two moieties, a benzimidazole and an aniline group. The benzimidazole and aniline planes are not coplanar, subtending a dihedral angle of 18.24 (8)degrees. The Zn(II) ion shows distorted tetrahedral geometry, being coordinated by an imidazole N atom, the aniline N atom, and two chlorido ligands. The packing features N-H center dot center dot center dot O, N-H center dot center dot center dot Cl, C-H center dot center dot center dot Cl hydrogen bonding.
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收藏
页码：491 / +
页数：9
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