Thermodynamic modeling for petroleum fluids - II. Prediction of PVT properties of oils and gases by fitting one or two parameters to the saturation pressures of reservoir fluids

被引:20
作者
Avaullee, L
Neau, E
Jaubert, JN
机构
[1] Fac Sci Luminy, Chim Phys Lab, F-13288 Marseille 9, France
[2] Ecole Natl Super Ind Chim, Inst Natl Polytech Lorraine, Lab Thermodynam Separat, F-54001 Nancy, France
关键词
method of calculation; equation of state; vapor-liquid equilibria; PVT properties; petroleum fluid;
D O I
10.1016/S0378-3812(97)00170-2
中图分类号
O414.1 [热力学];
学科分类号
摘要
This paper is devoted to the description of a method for modelling heavy cuts, using either a T.B.P. distillation or an advanced chromatography analysis method. Two sorts of reservoir fluids are defined depending on the advancement of the geochemical catagenetic reactions occurring during the history of the petroleum deposit. Given the existence of differences due to the geochemical history of fluids, two different thermodynamic characterizations may be computed from any given analytical information, One is generally more suitable for use with condensate gases and the other is more appropriate for calculating the physical properties of crude oils, The method presented here involves tuning one or two parameters to one of several saturation pressures of the reservoir fluid. This approach was tested on a data base including more than 50 reservoir fluids. In most cases, the PVT properties predicted using the above method were highly satisfactory. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:171 / 203
页数:33
相关论文
共 25 条
[1]   GROUP-CONTRIBUTION EQUATION OF STATE FOR CORRELATING AND PREDICTING THERMODYNAMIC PROPERTIES OF WEAKLY POLAR AND NONASSOCIATING MIXTURES - BINARY AND MULTICOMPONENT SYSTEMS [J].
ABDOUL, W ;
RAUZY, E ;
PENELOUX, A .
FLUID PHASE EQUILIBRIA, 1991, 68 :47-102
[2]  
ABDOUL W, 1987, THESIS U AIX MARSEIL
[3]   Thermodynamic modeling for petroleum fluids - I. Equation of state and group contribution for the estimation of thermodynamic parameters of heavy hydrocarbons [J].
Avaullee, L ;
Trassy, L ;
Neau, E ;
Jaubert, JN .
FLUID PHASE EQUILIBRIA, 1997, 139 (1-2) :155-170
[4]  
BLUMER M, 1976, SCI AM, V234, P34, DOI DOI 10.1038/SCIENTIFICAMERICAN0376-34
[5]   VAN DER WAALS VOLUMES + RADII [J].
BONDI, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+
[6]   Polycyclic aromatic hydrocarbons in the environment - Properties, origins, fate [J].
Bouchez, M ;
Blanchet, D ;
Haeseler, F ;
Vandecasteele, JP .
REVUE DE L INSTITUT FRANCAIS DU PETROLE, 1996, 51 (03) :407-419
[7]  
CARRIER B, 1989, THESIS U AIX MARSEIL
[8]   REPRESENTATION AND PREDICTION OF THERMOPHYSICAL PROPERTIES OF HEAVY HYDROCARBONS [J].
CONIGLIO, L ;
RAUZY, E ;
BERRO, C .
FLUID PHASE EQUILIBRIA, 1993, 87 (01) :53-88
[9]  
CONIGLIO L, 1993, THESIS U AIX MARSEIL
[10]   CHARACTERIZATION OF HEAVY OILS .2. DEFINITION OF A SIGNIFICANT CHARACTERIZING PARAMETER TO ENSURE THE RELIABILITY OF PREDICTIVE METHODS FOR PVT CALCULATIONS [J].
JAUBERT, JN ;
NEAU, E .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (05) :1873-1881