Synthesis and characterization of binuclear palladium(I) compounds and the influence of competing arenes

被引：16

作者：

Akerstedt, Josefin ^{[1
]}

Gorlov, Mikhail ^{[1
]}

Fischer, Andreas ^{[1
]}

Kloo, Lars ^{[1
]}

机构：

[1] Royal Inst Technol, Dept Inorgan Chem, S-10044 Stockholm, Sweden

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2010年 / 695卷 / 10-11期

基金：

瑞典研究理事会;

关键词：

Palladium; Gallium chloride; Arenes; Binuclear compounds; Crystal structure; STRUCTURAL-CHARACTERIZATION; METAL-CLUSTERS; COMPLEXES; BENZENE; GALLIUM; PSEUDOPOTENTIALS; CARBONYLATION; CHLORIDE; ELEMENTS; LIGANDS;

D O I：

10.1016/j.jorganchem.2010.03.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The binuclear palladium(I) compounds, [Pd(2)(Ga(2)Cl(7))(2)(C(7)H(8))(2)] (1), [Pd(2)(GaCl(4))(2)(C(9)H(12))(2)]center dot C(9)H(12) (2) and [Pd(2)(Ga(2)Cl(7))(2)(C(6)H(5)Cl)(2)] (3), have been prepared from palladium(II) chloride in gallium(III) chloride-arene reaction media. All isolated crystalline solids (1, 2 and 3) have been structurally characterized by single crystal X-ray diffraction and Raman spectroscopy. The results form quantum chemical calculations on the interaction energies of the arenes and the dipalladium unit of these compounds is also presented. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1513 / 1517

页数：5

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