The difference of roles of alkaline-earth metal oxides on silica-supported nickel catalysts for CO2 methanation

被引：82
作者：
Guo, Meng [1 ,2 ]
Lu, Gongxuan [1 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
RSC ADVANCES | 2014年 / 4卷 / 102期
基金：
中国国家自然科学基金;
关键词：
CARBON-DIOXIDE; PRODUCT DISTRIBUTION; NI/SIO2; CATALYST; COMPOSITE OXIDES; ACETIC-ACID; HYDROGENATION; NI; STABILITY; MECHANISM; SELECTIVITY;
D O I：
10.1039/c4ra06202g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The roles of alkaline-earth metal oxides on CO2 methanation over modified Ni/SiO2 catalysts were investigated. Ni/MO/SiO2 catalysts with variable elements (M = Mg, Ca, Sr and Ba) were prepared by the sequential impregnation method. The results indicated that the presence of SrO promoted the catalytic activity and enhanced the catalyst stability. In addition, BaO addition enhanced the reaction activity, but the Ni/BaO/SiO2 catalyst deactivated significantly after 50 h of time-on-stream due to the sintering of metallic Ni. Moreover, CaO addition affected negligibly the performance of the Ni/CaO/SiO2 catalyst, and MgO addition inhibited significantly the methanation performance because of the low reducibility of Ni species.
引用
收藏
页码：58171 / 58177
页数：7
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