Stereoselective synthesis of korupensamine A and ent-korupensamine B utilizing an identical planar chiral arene chromium complex

被引：0
|
作者：
Watanabe, T
Shakadou, M
Uemura, M [1 ]
机构：
[1] Univ Osaka Prefecture, Fac Integrated Arts & Sci, Dept Chem, Sakai, Osaka 5998531, Japan
[2] Univ Osaka Prefecture, Adv Sci & Technol Res Inst, Sakai, Osaka 5998570, Japan
来源：
SYNLETT | 2000年 / 08期
关键词：
alkaloids; arene chromium complexes; atropisomerism; cross-coupling; palladium;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Axially chiral naphthyltetrahydroisoquinoline alkaloids, korupensamines A and ent-korupensamine B, have been stereoselectively synthesized via palladium-catalyzed Suzuki-Miyaura cross-coupling of planar chiral tricarbonylchromium-complexed arylbromide with naphthylboronic acid.
引用
收藏
页码：1141 / 1144
页数：4
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