Palladium complexes bearing the dipyridyl ligand: synthesis, structural studies, and use in the Heck reaction

被引：1
作者：
Warad, Ismail [1 ]
Azam, Mohammad [2 ]
Al-Resayes, Saud I. [2 ]
Islam, Mohammad Shahidul [2 ]
Ahmed, Sarfaraz [3 ]
Haddad, Salim F. [4 ]
机构：
[1] AN Najah Natl Univ, Dept Chem, Coll Sci, POB 7, Nablus, Palestine
[2] King Saud Univ, Dept Chem, Coll Sci, POB 2455, Riyadh 11451, Saudi Arabia
[3] King Saud Univ, Dept Pharmacognosy, Coll Pharm, POB 2457, Riyadh 11451, Saudi Arabia
[4] Hashemite Univ, Dept Chem, Zarqa 13115, Jordan
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2016年 / 42卷 / 02期
关键词：
Di-2-pyridyl ketone (DPK); Crystal structure of the DPMNPH ligand; Palladium complexes; Heck reaction; OXIDATION; CATALYSTS; CD(II);
D O I：
10.1007/s11164-015-2256-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new palladium complexes derived from the di(2-pyridinyl)methanone N-(2-pyridinyl)hydrazone (DPMNPH) ligand are reported. The compounds were characterized by elemental analysis, spectroscopic studies, and, for the DPMNPH ligand, single-crystal X-ray diffraction analysis. The DPMNPH ligand crystallized as orthorhombic with the space group P2(1)2(1)2(1). The H1 atom is intramolecularly bonded to the pyridinic N4 with N1-H1 = 0.92(3) angstrom, H1 center dot center dot center dot N4 = 1.87(2) angstrom, N1 center dot center dot center dot N4 = 2.615(2) angstrom, and N1-H1 center dot center dot center dot N4 = 137(2)degrees. Both complexes were excellent catalysts in the Heck reaction in the presence of base.
引用
收藏
页码：379 / 389
页数：11
相关论文
共 50 条
[21]   Palladium Immobilized on 2,2′-Dipyridyl-Based Hypercrosslinked Polymers as a Heterogeneous Catalyst for Suzuki–Miyaura Reaction and Heck Reaction [J].
Cijie Liu ;
Wei Xu ;
Dexuan Xiang ;
Qionglin Luo ;
Shunqin Zeng ;
Lijuan Zheng ;
Yujie Tan ;
Yuejun Ouyang ;
Hongwei Lin .
Catalysis Letters, 2020, 150 :2558-2565
[22]   Diphosphinoazine palladium(II) complexes as catalysts for the Heck reaction of bromides and an activated chloride [J].
Vcelák, J ;
Storch, J ;
Czakóová, M ;
Cermák, J .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 222 (1-2) :121-126
[23]   Palladium N-methylimidazolium supported complexes as efficient catalysts for the Heck reaction [J].
Altava, B ;
Burguete, MI ;
García-Verdugo, E ;
Karbass, N ;
Luis, SV ;
Puzary, A ;
Sans, V .
TETRAHEDRON LETTERS, 2006, 47 (14) :2311-2314
[24]   Palladium complexes with bis(diphenylphosphinomethyl)amino ligands and their application as catalysts for the Heck reaction [J].
Mustafa Keleş ;
Tuğba Keleş ;
Osman Serindağ .
Transition Metal Chemistry, 2008, 33 :717-720
[25]   Study of “ligand-free” catalytic systems with low palladium content for the Heck reaction [J].
V. V. Smirnov ;
A. Al Halaiqa ;
A. F. Shmidt .
Russian Journal of Applied Chemistry, 2010, 83 :453-457
[26]   N, N'-bidentate ligand anchored palladium catalysts on MOFs for efficient Heck reaction [J].
Xu, Xiao-Li ;
Wang, Nian-Nian ;
Zou, Yong-Hao ;
Qin, Xiao ;
Wang, Peng ;
Lu, Xiang-Yu ;
Zhang, Xiao-Yu ;
Sun, Wei-Yin ;
Lu, Yi .
NATURE COMMUNICATIONS, 2024, 15 (01)
[27]   Palladium-catalyzed synthesis of indoles via intramolecular Heck reaction [J].
Yang, Hailong ;
Sun, Peng ;
Zhu, Yan ;
Yan, Hong ;
Lu, Linhua ;
Liu, Defu ;
Rong, Guangwei ;
Mao, Jincheng .
CATALYSIS COMMUNICATIONS, 2013, 38 :21-25
[28]   Synthesis of Oxathiocine Derivatives by Palladium-Catalyzed Intramolecular Heck Reaction [J].
Majumdar, K. C. ;
Chattopadhyay, Buddhadeb ;
Sinha, Biswajit .
LETTERS IN ORGANIC CHEMISTRY, 2009, 6 (06) :453-455
[29]   Palladium(II) complexes with P,N- and C,N-ligands as catalysts for the Heck reaction [J].
Schultz, T ;
Schmees, N ;
Pfaltz, A .
APPLIED ORGANOMETALLIC CHEMISTRY, 2004, 18 (11) :595-601
[30]   Palladium Immobilized on 2,2′-Dipyridyl-Based Hypercrosslinked Polymers as a Heterogeneous Catalyst for Suzuki-Miyaura Reaction and Heck Reaction [J].
Liu, Cijie ;
Xu, Wei ;
Xiang, Dexuan ;
Luo, Qionglin ;
Zeng, Shunqin ;
Zheng, Lijuan ;
Tan, Yujie ;
Ouyang, Yuejun ;
Lin, Hongwei .
CATALYSIS LETTERS, 2020, 150 (09) :2558-2565
12345