The Future of Using Earth-Abundant Elements in Counter Electrodes for Dye-Sensitized Solar Cells

被引:101
作者
Briscoe, Joe [1 ]
Dunn, Steve [1 ]
机构
[1] Queen Mary Univ London, Mat Res Inst, Sch Engn & Mat Sci, Mile End Rd, London E1 4NS, England
关键词
LEAD-ZIRCONATE-TITANATE; LOW-COST; PHOTOCHEMICAL REACTIVITY; PHOTOCATALYTIC ACTIVITY; PIEZOFORCE MICROSCOPY; BIFEO3; NANOPARTICLES; FERROELECTRIC BATIO3; CARBON NANOTUBES; RECENT PROGRESS; GRAPHENE OXIDE;
D O I
10.1002/adma.201504085
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
With limited global resources for many of the elements that are found in some of the most common renewable energy technologies, there is a growing need to use "Earth-abundant" elements as a long-term solution to growing energy demands. The dye-sensitized solar cell has the potential to produce low-cost renewable energy, with inexpensive production and most components using Earth-abundant elements. However, the most commonly used material for the cell counter electrode (CE) is platinum, an extremely expensive and rare element. A selection of the materials investigated as alternative CEs are discussed, including metal sulfides, oxides, carbides, and nitrides and carbon-based materials such as carbon nanotubes, graphene, and conductive polymers. As well as having the potential for lower cost, these materials can also produce more-efficient devices due to their high surface area and catalytic activity. Therefore, once issues such as stability have been studied in more detail and scale-up of production methods are considered, there is a very promising future for the replacement of Pt in DSSCs with lower-cost, Earth-abundant alternatives.
引用
收藏
页码:3802 / 3813
页数:12
相关论文
共 87 条
[1]  
[Anonymous], 2010, ANGEW CHEM, DOI DOI 10.1002/ANGE.201003110
[2]   Piezoelectric and ferroelectric materials and structures for energy harvesting applications [J].
Bowen, C. R. ;
Kim, H. A. ;
Weaver, P. M. ;
Dunn, S. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (01) :25-44
[3]   Extremely thin absorber solar cells based on nanostructured semiconductors [J].
Briscoe, J. ;
Dunn, S. .
MATERIALS SCIENCE AND TECHNOLOGY, 2011, 27 (12) :1741-1756
[4]   Biomass-Derived Carbon Quantum Dot Sensitizers for Solid-State Nanostructured Solar Cells [J].
Briscoe, Joe ;
Marinovic, Adam ;
Sevilla, Marta ;
Dunn, Steve ;
Titirici, Magdalena .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (15) :4463-4468
[5]   Photochemical Reactivity of Titania Films on BaTiO3 Substrates: Influence of Titania Phase and Orientation [J].
Burbure, Nina V. ;
Salvador, Paul A. ;
Rohrer, Gregory S. .
CHEMISTRY OF MATERIALS, 2010, 22 (21) :5831-5837
[6]   Photochemical Reactivity of Titania Films on BaTiO3 Substrates: Origin of Spatial Selectivity [J].
Burbure, Nina V. ;
Salvador, Paul A. ;
Rohrer, Gregory S. .
CHEMISTRY OF MATERIALS, 2010, 22 (21) :5823-5830
[7]   Emergence of Hysteresis and Transient Ferroelectric Response in Organo-Lead Halide Perovskite Solar Cells [J].
Chen, Hsin-Wei ;
Sakai, Nobuya ;
Ikegami, Masashi ;
Miyasaka, Tsutomu .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (01) :164-169
[8]   Switchable Ferroelectric Diode and Photovoltaic Effect in BiFeO3 [J].
Choi, T. ;
Lee, S. ;
Choi, Y. J. ;
Kiryukhin, V. ;
Cheong, S. -W. .
SCIENCE, 2009, 324 (5923) :63-66
[9]   Photodegradation of Rhodamine B over Ag modified ferroelectric BaTiO3 under simulated solar light: pathways and mechanism [J].
Cui, Yongfei ;
Goldup, Stephen M. ;
Dunn, Steve .
RSC ADVANCES, 2015, 5 (38) :30372-30379
[10]   Effect of Ferroelectricity on Solar-Light-Driven Photocatalytic Activity of BaTiO3-Influence on the Carrier Separation and Stern Layer Formation [J].
Cui, Yongfei ;
Briscoe, Joe ;
Dunn, Steve .
CHEMISTRY OF MATERIALS, 2013, 25 (21) :4215-4223