Optimizing Catalyst and Reaction Conditions in Gold(I) Catalysis-Ligand Development

被引：117
作者：
Collado, Alba [1 ]
Nelson, David J. [2 ]
Nolan, Steven P. [3 ,4 ]
机构：
[1] Univ Autonoma Madrid, Dept Quim Inorgan, Madrid 28049, Spain
[2] Univ Strathclyde, WestCHEM Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland
[3] Univ Ghent, Dept Chem, B-9000 Ghent, Belgium
[4] Univ Ghent, Ctr Sustainable Chem, B-9000 Ghent, Belgium
来源：
CHEMICAL REVIEWS | 2021年 / 121卷 / 14期
关键词：
N-HETEROCYCLIC CARBENE; CYCLIC (ALKYL)(AMINO)CARBENES CAACS; NITROGEN ACYCLIC CARBENES; PI-ACCEPTOR PROPERTIES; WATER-SOLUBLE GOLD(I); ONE-POT SYNTHESIS; TERMINAL ALKYNES; ROOM-TEMPERATURE; ELECTRONIC-PROPERTIES; NHC LIGANDS;
D O I：
10.1021/acs.chemrev.0c01320
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This review considers phosphine and N-heterocyclic carbene complexes of gold(I) that are used as (pre)catalysts for a range of reactions in organic synthesis. These are divided according to the structure of the ligand, with the narrative focusing on studies that offer a quantitative comparison between the ligands and readily available or widely used existing systems.
引用
收藏
页码：8559 / 8612
页数：54
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