Optimizing Catalyst and Reaction Conditions in Gold(I) Catalysis-Ligand Development

被引：117

作者：

Collado, Alba ^{[1
]}

Nelson, David J. ^{[2
]}

Nolan, Steven P. ^{[3
,4
]}

机构：

[1] Univ Autonoma Madrid, Dept Quim Inorgan, Madrid 28049, Spain

[2] Univ Strathclyde, WestCHEM Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[3] Univ Ghent, Dept Chem, B-9000 Ghent, Belgium

[4] Univ Ghent, Ctr Sustainable Chem, B-9000 Ghent, Belgium

来源：

CHEMICAL REVIEWS | 2021年 / 121卷 / 14期

关键词：

N-HETEROCYCLIC CARBENE; CYCLIC (ALKYL)(AMINO)CARBENES CAACS; NITROGEN ACYCLIC CARBENES; PI-ACCEPTOR PROPERTIES; WATER-SOLUBLE GOLD(I); ONE-POT SYNTHESIS; TERMINAL ALKYNES; ROOM-TEMPERATURE; ELECTRONIC-PROPERTIES; NHC LIGANDS;

D O I：

10.1021/acs.chemrev.0c01320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review considers phosphine and N-heterocyclic carbene complexes of gold(I) that are used as (pre)catalysts for a range of reactions in organic synthesis. These are divided according to the structure of the ligand, with the narrative focusing on studies that offer a quantitative comparison between the ligands and readily available or widely used existing systems.

引用

页码：8559 / 8612

页数：54

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