Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1)

被引：39

作者：

Mori, Shigeki ^{[1
]}

Shimizu, Soji ^{[1
]}

Shin, Ji-Young ^{[1
]}

Osuka, Atsuhiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 11期

关键词：

D O I：

10.1021/ic7004216

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metalation of meso-hexakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1) (1) has been explored with group 12 metal ions Zn(II), Cd(II), and Hg(II). Zn(II) and Cd(II) ions afforded dinuclear gable-shaped complexes 2 and 3 in good yields, while Hg(II) ion provided bis-Hg(II) and mono-Hg(II) planar complexes (4 and 5) via C-H bond cleavage.

引用

页码：4374 / 4376

页数：3

共 30 条

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