Slippery Liquid Infused Porous TiO2/SnO2 Nanocomposite Thin Films via Aerosol Assisted Chemical Vapor Deposition with Anti-Icing and Fog Retardant Properties

被引：41
作者：
Heale, Frances L. [1 ]
Parkin, Ivan P. [1 ]
Carmalt, Claire J. [1 ]
机构：
[1] UCL, Dept Chem, 20 Gordon St, London WC1H OAJ, England
来源：
ACS APPLIED MATERIALS & INTERFACES | 2019年 / 11卷 / 44期
基金：
“创新英国”项目; 英国工程与自然科学研究理事会;
关键词：
thin films; SLIPS; anti-icing antifogging; TiO2/SnO2; nanocomposites; AACVD; REGENERABLE SUPERHYDROPHOBIC COATINGS; ICE ADHESION; SURFACES; WATER; METAL;
D O I：
10.1021/acsami.9b14160
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Exceptional anti-icing and antifogging devices have been synthesized through combination of micro- and/or nanoscale hierarchical thin films followed by a modification with a surface lubricant. Aerosol assisted chemical vapor deposition (AACVD) of single source titanium and tin precursors generated titanium dioxide (TiO2)/tin dioxide (SnO2) composite thin films. Variation in solvent type and/or combination notably impacted on the resulting intricate surface morphologies, which, upon Krytox lubricant modification, generated slippery liquid infused porous surfaces (SLIPS). The surface topography had a profound effect on the degree of surface ice and fog accumulation. The highest functioning films comprised of hybrid spherical/flowery surface structures generated using a mixed ethyl acetate/dichloromethane solvent system. These films retarded ice formation for >30 min at -10 degrees C and maintained a high level of sample transparency upon suspension above a heated water bath.
引用
收藏
页码：41804 / 41812
页数：9
相关论文
共 36 条
  • [1] Superhydrophobic and photocatalytic self-cleaning cotton
    Afzal, Shabana
    Daoud, Walid A.
    Langford, Steven J.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (42) : 18005 - 18011
  • [2] Dynamics of Ice Nucleation on Water Repellent Surfaces
    Alizadeh, Azar
    Yamada, Masako
    Li, Ri
    Shang, Wen
    Otta, Shourya
    Zhong, Sheng
    Ge, Liehui
    Dhinojwala, Ali
    Conway, Ken R.
    Bahadur, Vaibhav
    Vinciquerra, A. Joseph
    Stephens, Brian
    Blohm, Margaret L.
    [J]. LANGMUIR, 2012, 28 (06) : 3180 - 3186
  • [3] Beamson G., 1992, High Resolution XPS of Organic Polymers. The Scienta ESCA300 Database, DOI [DOI 10.1021/ED070PA25.5, 10.1021/ed070pA25.5]
  • [4] Carriveau R, 2012, J ADHES SCI TECHNOL, V26, P447, DOI [10.1163/016942411X574592, 10.1163/016942411x574592]
  • [5] Combinatorial aerosol assisted chemical vapour deposition of a photocatalytic mixed SnO2/TiO2 thin film
    Chadwick, Nicholas
    Sathasivam, Sanjayan
    Kafizas, Andreas
    Bawaked, Salem M.
    Obaid, Abdullah Y.
    Al-Thabaiti, Shaeel
    Basahel, Sulaiman N.
    Parkin, Ivan P.
    Carmalt, Claire J.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (14) : 5108 - 5116
  • [6] Preparation and Characterisation of Super-Hydrophobic Surfaces
    Crick, Colin R.
    Parkin, Ivan P.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (12) : 3568 - 3588
  • [7] Estimation of the energetic and environmental impacts of a roof-mounted building-integrated photovoltaic systems
    Cucchiella, Federica
    D'Adamo, Idiano
    [J]. RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2012, 16 (07) : 5245 - 5259
  • [8] Anti-icing Coating with an Aqueous Lubricating Layer
    Dou, Renmei
    Chen, Jing
    Zhang, Yifan
    Wang, Xupeng
    Cui, Dapeng
    Song, Yanlin
    Jiang, Lei
    Wang, Jianjun
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (10) : 6998 - 7003
  • [9] Aircraft icing
    Gent, RW
    Dart, NP
    Cansdale, JT
    [J]. PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2000, 358 (1776): : 2873 - 2911
  • [10] Self-cleaning and next generation anti-fog surfaces and coatings
    Howarter, John A.
    Youngblood, Jeffrey P.
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2008, 29 (06) : 455 - 466
1234