Full Factorial Design Approach to Hg(II) Adsorption onto Hydrogels

被引:17
作者
Bingol, Deniz [1 ]
Saraydin, Dursun [2 ]
Ozbay, Dilek Solpan [3 ]
机构
[1] Kocaeli Univ, Fac Sci & Art, Dept Chem, Kocaeli, Turkey
[2] Cumhuriyet Univ, Fac Sci, Dept Chem, Sivas, Turkey
[3] Hacettepe Univ, Dept Chem, Fac Sci, TR-06532 Ankara, Turkey
关键词
Hydrogel; Mercury; Response surface method; Wastewater; REMOVAL; OPTIMIZATION; MERCURY(II); SORPTION; DYE;
D O I
10.1007/s13369-014-1484-x
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
A 2(4) factorial design was used to evaluate the quantitative adsorption of Hg(II) ions in an aqueous solution onto radiation crosslinked poly(acrylic acid/acrylamide) hydrogels. The influence on the binding ratio (r) of variables such as pH, temperature, initial concentration of solution, and material was analyzed statistically using a suggested regression equation. The results demonstrate that the initial concentration of Hg(II) is the most significant parameter. A maximum Hg(II) ion uptake of 15.50 mg/g (with standard deviation, 0.20) was achieved at a high initial Hg(II) concentration (100 mg/L), low pH (2.5), and low temperature (15 A degrees C) for both of radiation crosslinked poly(AAm-co-AAc) hydrogel samples in a significance level of 5%.
引用
收藏
页码:109 / 116
页数:8
相关论文
共 21 条
[1]   Factorial experimental design for biosorption of iron and zinc using Typha domingensis phytomass [J].
Abdel-Ghani, N. T. ;
Hegazy, Ahmad K. ;
El-Chaghaby, G. A. ;
Lima, Eder C. .
DESALINATION, 2009, 249 (01) :343-347
[2]   Factorial design analysis for adsorption of dye on activated carbon beads incorporated with calcium alginate [J].
Annadurai, G ;
Juang, RS ;
Lee, DJ .
ADVANCES IN ENVIRONMENTAL RESEARCH, 2002, 6 (02) :191-198
[3]   Graft copolymer of acrylamide onto cellulose as mercury selective sorbent [J].
Biçak, N ;
Sherrington, DC ;
Senkal, BF .
REACTIVE & FUNCTIONAL POLYMERS, 1999, 41 (1-3) :69-76
[4]   Mercury(II) removal from aqueous solution by sorption onto alginate, pectate and polygalacturonate calcium gel beads. A kinetic and speciation based equilibrium study [J].
Cataldo, Salvatore ;
Gianguzza, Antonio ;
Pettignano, Alberto ;
Villaescusa, Isabel .
REACTIVE & FUNCTIONAL POLYMERS, 2013, 73 (01) :207-217
[5]   Studies on Hg(II) ion retention properties of cross-linked graft copolymer of acrylic acid and its analytical application [J].
Chowdhury, Pranesh ;
Mukherjee, Abhijit ;
Singha, B. ;
Mondal, Palash ;
Roy, Kousik .
JOURNAL OF POLYMER RESEARCH, 2010, 17 (06) :853-860
[6]   Adsorption of aqueous Hg(II) by a polyaniline/attapulgite composite [J].
Cui, Hao ;
Qian, Yan ;
Li, Qin ;
Zhang, Qiu ;
Zhai, Jianping .
CHEMICAL ENGINEERING JOURNAL, 2012, 211 :216-223
[7]   Application of multivariate techniques in optimization of spectroanalytical methods [J].
Ferreira, Sergio Luis Costa ;
Andrade Korn, Maria das Gracas ;
Ferreira, Hadla Sousa ;
da Silva, Erik Galvao Paranhos ;
Araujo, Rennan Geovanny Oliveira ;
Souza, Anderson Santos ;
Macedo, Samuel Marques ;
de Castro Lima, Daniel ;
de Jesus, Raildo Mota ;
Amorim, Fabio Alan Carqueija ;
Bosque-Sendra, Juan Manuel .
APPLIED SPECTROSCOPY REVIEWS, 2007, 42 (05) :475-491
[8]   Mercury sorption on a thiocarbamoyl derivative of chitosan [J].
Gavilan, K. Campos ;
Pestov, A. V. ;
Garcia, H. Maldonado ;
Yatluk, Y. ;
Roussy, Jean ;
Guibal, E. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 165 (1-3) :415-426
[9]   Experimental design and optimization [J].
Lundstedt, T ;
Seifert, E ;
Abramo, L ;
Thelin, B ;
Nystrom, A ;
Pettersen, J ;
Bergman, R .
CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, 1998, 42 (1-2) :3-40
[10]  
Montgomery D., 2013, DESIGN ANAL EXPT, V8