Oligo(ethylene glycol)-incorporated hybrid linear alkyl side chains for n-channel polymer semiconductors and their effect on the thin-film crystalline structure

被引：46

作者：

Kim, Ran ^{[1
,2
]}

Kang, Boseok ^{[3
,4
]}

Sin, Dong Hun ^{[3
,4
]}

Choi, Hyun Ho ^{[3
,4
]}

Kwon, Soon-Ki ^{[5
,6
]}

Kim, Yun-Hi ^{[5
,6
]}

Cho, Kilwon ^{[3
,4
]}

机构：

[1] Gyeongsang Natl Univ, Dept Chem, Jinju 660701, South Korea

[2] Gyeongsang Natl Univ, RINS, Jinju 660701, South Korea

[3] Pohang Univ Sci & Technol POSTECH, Dept Chem Engn, Pohang 790784, South Korea

[4] Ctr Adv Soft Elect, Pohang 790784, South Korea

[5] Gyeongsang Natl Univ, Sch Mat Sci & Engn, Jinju 660701, South Korea

[6] Gyeongsang Natl Univ, ERI, Jinju 660701, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 08期

关键词：

FIELD-EFFECT TRANSISTORS; CHARGE-CARRIER MOBILITY; CONJUGATED POLYMERS; PERFORMANCE; TRANSPORT; COPOLYMERS; ELECTRON; IMPACT;

D O I：

10.1039/c4cc08381d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oligo(ethylene glycol)-incorporated hybrid linear alkyl side chains, serving as solubilizing groups, are designed and introduced into naphthalene-diimide-based n-channel copolymers. The synthesized polymers exhibit unipolar n-type operation with an electron mobility of up to 1.64 cm(2) V-1 s(-1), which demonstrates the usefulness of the hybrid side chains in polymer electronics applications.

引用

页码：1524 / 1527

页数：4

共 23 条

[1] Solvent Additive to Achieve Highly Ordered Nanostructural Semicrystalline DPP Copolymers: Toward a High Charge Carrier Mobility [J].

An, Tae Kyu ;

Kang, Il ;

Yun, Hui-jun ;

Cha, Hyojung ;

Hwang, Jihun ;

Park, Seonuk ;

Kim, Jiye ;

Kim, Yu Jin ;

Chung, Dae Sung ;

Kwon, Soon-Ki ;

Kim, Yun-Hi ;

Park, Chan Eon .

ADVANCED MATERIALS, 2013, 25 (48) :7003-7009

[2] Towards understanding the behavior of indigo thin films in organic field-effect transistors: a template effect of the aliphatic hydrocarbon dielectric on the crystal structure and electrical performance of the semiconductor [J].

Anokhin, Denis V. ;

Leshanskaya, Lidiya I. ;

Piryazev, Alexey A. ;

Susarova, Diana K. ;

Dremova, Nadezhda N. ;

Shcheglov, Evgeniy V. ;

Ivanov, Dimitri A. ;

Razumov, Vladimir F. ;

Troshin, Pavel A. .

CHEMICAL COMMUNICATIONS, 2014, 50 (57) :7639-7641

[3] Naphthalenediimide-Based Copolymers Incorporating Vinyl-Linkages for High-Performance Ambipolar Field-Effect Transistors and Complementary-Like Inverters under Air (vol 25, pg 3589, 2013) [J].

Chen, Huajie ;

Guo, Yunlong ;

Mao, Zupan ;

Yu, Gui ;

Huang, Jianyao ;

Zhao, Yan ;

Liu, Yunqi .

CHEMISTRY OF MATERIALS, 2013, 25 (23) :4835-4835

[4] Printable ion-gel gate dielectrics for low-voltage polymer thin-film transistors on plastic [J].

Cho, Jeong Ho ;

Lee, Jiyoul ;

Xia, Yu ;

Kim, Bongsoo ;

He, Yiyong ;

Renn, Michael J. ;

Lodge, Timothy P. ;

Frisbie, C. Daniel .

NATURE MATERIALS, 2008, 7 (11) :900-906

[5] Side chain engineering of n-type conjugated polymer enhances photocurrent and efficiency of all-polymer solar cells [J].

Hwang, Ye-Jin ;

Earmme, Taeshik ;

Subramaniyan, Selvam ;

Jenekhe, Samson A. .

CHEMICAL COMMUNICATIONS, 2014, 50 (74) :10801-10804

[6] Enhancing 2D growth of organic semiconductor thin films with macroporous structures via a small-molecule heterointerface [J].

Kang, Boseok ;

Jang, Moonjeong ;

Chung, Yoonyoung ;

Kim, Haena ;

Kwak, Sang Kyu ;

Oh, Joon Hak ;

Cho, Kilwon .

NATURE COMMUNICATIONS, 2014, 5

[7] Recent Advances in Organic Transistor Printing Processes [J].

Kang, Boseok ;

Lee, Wi Hyoung ;

Cho, Kilwon .

ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (07) :2302-2315

[8] Diketopyrrolopyrrole-Diketopyrrolopyrrole-Based Conjugated Copolymer for High-Mobility Organic Field-Effect Transistors [J].

Kanimozhi, Catherine ;

Yaacobi-Gross, Nir ;

Chou, Kang Wei ;

Amassian, Aram ;

Anthopoulos, Thomas D. ;

Patil, Satish .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (40) :16532-16535

[9] High-Mobility Air-Stable Naphthalene Diimide-Based Copolymer Containing Extended π-Conjugation for n-Channel Organic Field Effect Transistors [J].

Kim, Ran ;

Amegadze, Paul S. K. ;

Kang, Il ;

Yun, Hui-Jun ;

Noh, Yong-Young ;

Kwon, Soon-Ki ;

Kim, Yun-Hi .

ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (46) :5719-5727

[10] Highly oriented crystals at the buried interface in polythiophene thin-film transistors [J].

Kline, RJ ;

Mcgehee, MD ;

Toney, MF .

NATURE MATERIALS, 2006, 5 (03) :222-228

← 1 2 3 →