Shape Complementary Coordination Self-Assembly of a Redox-Active Heteroleptic Complex

被引：8

作者：

Xuan, Jin-Jin ^{[1
,2
]}

Xia, Zi-Jun ^{[1
,2
]}

Yan, Dan-Ni ^{[2
]}

Hu, Shao-Jun ^{[2
]}

Zhou, Li-Peng ^{[2
]}

Cai, Li-Xuan ^{[1
,2
]}

Sun, Qing-Fu ^{[1
,2
]}

机构：

[1] Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

INORGANIC CHEMISTRY | 2022年 / 61卷 / 23期

基金：

中国国家自然科学基金;

关键词：

MOLECULAR CAPSULE; DIELS-ALDER; BINDING; DIVERSITY; PRISM; HOSTS;

D O I：

10.1021/acs.inorgchem.2c00872

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We present here the coordination self-assembly of a new heteroleptic (bpyPd)(4)(LL22)-L-1 coordination complex (1) from one novel pyridinium-functionalized bis-2,4,6-tris(pyridin-3-yl)-1,3,5-triazine (bis-3-TPT, L-1) macrocyclic ligand, two separate 3-TPT (L-2) ligands, and four cis-blocking bpyPd(NO3)(2) (bpy = 2,2'-bipyridine). While homoleptic self-assemblies with either L-1 or L-2 gave dynamic mixtures of products, a single thermodynamic heteroleptic complex was obtained driven by the shape complementarity of building blocks. Moreover, the redox-active nature of the heteroleptic assembly facilitates the highly efficient catalytic aerobic photo-oxidation of aromatic secondary alcohols under mild conditions.

引用

页码：8854 / 8860

页数：7

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