Non-Solvating and Low-Dielectricity Cosolvent for Anion-Derived Solid Electrolyte Interphases in Lithium Metal Batteries

被引:241
作者
Ding, Jun-Fan [1 ,2 ]
Xu, Rui [1 ,2 ]
Yao, Nan [3 ]
Chen, Xiang [3 ]
Xiao, Ye [1 ,2 ]
Yao, Yu-Xing [3 ]
Yan, Chong [1 ,2 ,3 ]
Xie, Jin [3 ]
Huang, Jia-Qi [1 ,2 ]
机构
[1] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
[2] Beijing Inst Technol, Adv Res Inst Multidisciplinary Sci, Beijing 100081, Peoples R China
[3] Tsinghua Univ, Dept Chem Engn, Beijing 100084, Peoples R China
基金
北京市自然科学基金; 中国国家自然科学基金;
关键词
anion– cation interaction; cation solvation; lithium metal batteries; low-dielectricity cosolvent; solid electrolyte interphase;
D O I
10.1002/anie.202101627
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lithium (Li) metal anodes hold great promise for next-generation high-energy-density batteries, while the insufficient fundamental understanding of the complex solid electrolyte interphase (SEI) is the major obstacle for the full demonstration of their potential in working batteries. The characteristics of SEI highly depend on the inner solvation structure of lithium ions (Li+). Herein, we clarify the critical significance of cosolvent properties on both Li+ solvation structure and the SEI formation on working Li metal anodes. Non-solvating and low-dielectricity (NL) cosolvents intrinsically enhance the interaction between anion and Li+ by affording a low dielectric environment. The abundant positively charged anion-cation aggregates generated as the introduction of NL cosolvents are preferentially brought to the negatively charged Li anode surface, inducing an anion-derived inorganic-rich SEI. A solvent diagram is further built to illustrate that a solvent with both proper relative binding energy toward Li+ and dielectric constant is suitable as NL cosolvent.
引用
收藏
页码:11442 / 11447
页数:6
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