Magnetic properties of LaNi1-xMnxO3+δ perovskites

被引:35
作者
Blasco, J [1 ]
García, J
Sánchez, MC
Campo, J
Subías, G
Pérez-Cacho, J
机构
[1] CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain
[2] CSIC, Dept Fis Mat Condensada, E-50009 Zaragoza, Spain
[3] Univ Zaragoza, E-50009 Zaragoza, Spain
[4] Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France
[5] European Synchrotron Radiat Facil, F-38043 Grenoble, France
关键词
D O I
10.1140/epjb/e2002-00403-7
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Magnetic measurements have been carried out in different LaNi1-xMnxO3+delta samples with 0.1 less than or equal to x less than or equal to 0.9. All these samples show two magnetic anomalies, one at relatively high temperature characteristic of a ferromagnetic ordering and the other at low temperature, typical of magnetic relaxation phenomena. Neutron diffraction patterns indicate that long-range ferromagnetic ordering is only achieved for x greater than or equal to 0.5. Neutron patterns of LaNi0.5Mn0.5O3+delta samples show an ordered arrangement of Ni and Mn atoms in the perovskite lattice. LaNi0.5Mn0.5O3+delta is then, a double perovskite A(2)BB'O-6 whereas Ni and Mn atoms are randomly distributed for the rest of the samples. X-ray magnetic circular dichroism experiments confirm the presence of collinear ferromagnetism in LaNi0.5Mn0.5O3+delta. The role of competitive magnetic interactions, structural disorder, magnetic anisotropy and magnetic disaccommodation is also discussed.
引用
收藏
页码:469 / 479
页数:11
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