Zinc and cadmium complexes of pyridyl-benzotriazole: Syntheses, structures and supramolecular interaction

被引:8
|
作者
Wang, Fei [1 ]
Wu, Xiao-Yuan [1 ]
Zhao, Zhen-Guo [1 ]
Zhang, Qi-Sheng [1 ]
Xie, Yi-ming [1 ]
Yu, Rongmin [1 ]
Lu, Can-Zhong [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
Benzotriazole; Hydrogen bonding; pi-pi Interaction; Supramolecular framework; CRYSTAL-STRUCTURE; COORDINATION POLYMERS; FLUORIDE; NETWORK; ROUTES; COPPER; MOLECULES; CLUSTERS; CHAIN; SPIN;
D O I
10.1016/j.ica.2009.12.060
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Five novel complexes with two pyridine substituted benzotriazole ligands, 1-(2-pyridyl)benzotriazole (L1) and 1-(4-pyridyl)benzotriazole (L2), [Zn(L-1)(2)Cl-2](1), [{Zn(L-1)(2)Cl-2} (C)(L1)2](2), [Zn(L-2)(2)Cl-2](3), [{Zn(L2)(H2O)(3)(mu(2)-SO4)}center dot H2O] (4), and [{Cd(L2)(H2O)(3)(mu(2)-SO4)}center dot H2O](5) were synthesized. The details of the structures were characterized by X-ray single crystal analysis, revealing that these complexes were assembled together via supramolecular interaction, such as, hydrogen bonding and pi-pi interactions. The influence of organic ligands, anions and reaction conditions in the formation of the complexes were investigated. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1320 / 1324
页数:5
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