Zinc and cadmium complexes of pyridyl-benzotriazole: Syntheses, structures and supramolecular interaction

被引：8

作者：

Wang, Fei ^{[1
]}

Wu, Xiao-Yuan ^{[1
]}

Zhao, Zhen-Guo ^{[1
]}

Zhang, Qi-Sheng ^{[1
]}

Xie, Yi-ming ^{[1
]}

Yu, Rongmin ^{[1
]}

Lu, Can-Zhong ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Benzotriazole; Hydrogen bonding; pi-pi Interaction; Supramolecular framework; CRYSTAL-STRUCTURE; COORDINATION POLYMERS; FLUORIDE; NETWORK; ROUTES; COPPER; MOLECULES; CLUSTERS; CHAIN; SPIN;

D O I：

10.1016/j.ica.2009.12.060

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five novel complexes with two pyridine substituted benzotriazole ligands, 1-(2-pyridyl)benzotriazole (L1) and 1-(4-pyridyl)benzotriazole (L2), [Zn(L-1)(2)Cl-2](1), [{Zn(L-1)(2)Cl-2} (C)(L1)2](2), [Zn(L-2)(2)Cl-2](3), [{Zn(L2)(H2O)(3)(mu(2)-SO4)}center dot H2O] (4), and [{Cd(L2)(H2O)(3)(mu(2)-SO4)}center dot H2O](5) were synthesized. The details of the structures were characterized by X-ray single crystal analysis, revealing that these complexes were assembled together via supramolecular interaction, such as, hydrogen bonding and pi-pi interactions. The influence of organic ligands, anions and reaction conditions in the formation of the complexes were investigated. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1320 / 1324

页数：5

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