Synthesis of dendritic PdAu nanoparticles with enhanced electrocatalytic activity

被引:24
作者
Hong, Wei [1 ,2 ]
Shang, Changshuai [1 ,2 ]
Wang, Jin [1 ,3 ]
Wang, Erkang [1 ,2 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
[3] SUNY Stony Brook, Dept Chem & Phys, Stony Brook, NY 11794 USA
基金
中国国家自然科学基金;
关键词
Dendritic; Palladium; Gold; Electrooxidation; Catalytic activity; BIMETALLIC NANODENDRITES; ETHANOL; CATALYSTS; NANOCRYSTALS;
D O I
10.1016/j.elecom.2014.08.017
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A facile method for the rapid synthesis of dendritic PdAu alloyed bimetallic nanocrystals is demonstrated. The whole synthetic process is very simple just by mixing Na2PdCl4, HAuCl4, polyvinylpyrrolidone and hydroquinone and heated at 50 degrees C for 15 min. The as-prepared dendritic PdAu nanoparticles exhibit superior catalytic activity for methanol, ethanol and glycerol electrooxidation in alkaline solution, and their catalytic performance is composition-dependent. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:65 / 68
页数:4
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