Structure-directed materials syntheses: Metal complexes as structure-directing agents for zeolite-type solids

被引:8
作者
Behrens, P [1 ]
Panz, C [1 ]
Hufnagel, V [1 ]
Lindlar, B [1 ]
Freyhardt, CC [1 ]
van de Goor, G [1 ]
机构
[1] Univ Munich, Inst Anorgan Chem, D-80333 Munich, Germany
关键词
structure-directed synthesis; structure-directing agents; clathrasils; zeosils; hydrothermal method;
D O I
10.1016/S0167-2738(97)00365-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metal complexes have been discovered as a novel class of structure-directing agents for the synthesis of porosils, i.e. zeolite-type solids with a pure silica framework. A survey is given about the different preparation methods used and the silica-metal complex host-guest compounds that have been synthesized so far. Special attention is given to differences between cobalticinium nonasil compounds that have been synthesized in basic or fluoride media.
引用
收藏
页码:229 / 234
页数:6
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