Kinetics of zirconium saturation with nitrogen during high-temperature nitridation

被引：7

作者：

Kuznetsov, K. B. ^{[1
]}

Kovalev, I. A. ^{[1
]}

Zufman, V. Yu ^{[1
]}

Ogarkov, A. I. ^{[1
]}

Shevtsov, S. V. ^{[1
]}

Ashmarin, A. A. ^{[1
]}

Chernyavskii, A. S. ^{[1
]}

Solntsev, K. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Baikov Inst Met & Mat Sci, Leninskii Pr 49, Moscow 119991, Russia

来源：

INORGANIC MATERIALS | 2016年 / 52卷 / 06期

基金：

俄罗斯科学基金会;

关键词：

zirconium nitride; nitridation; oxidation-assisted engineering; ceramic; kinetics;

D O I：

10.1134/S0020168516060078

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Zirconium samples in the form of ribbons 60 mm in length and 3.0 x 0.5 mm in cross section were heated in a nitrogen atmosphere at temperatures of 1500, 1800, 1965, and 2400A degrees C. The nitridation time at each temperature was 4, 6, 11, 21, 30, 40, 50, and 60 min. It has been shown that, under the thermal conditions studied, the process of saturation with nitrogen involves two stages: the first stage (in which the metallic phase disappears) can be represented by an exponential rate law, and the second (corresponding to an increase in nitrogen content up to the stoichiometric composition of ZrN) has a linear rate law.

引用

页码：558 / 560

页数：3

共 50 条

[31] Optimization of time-temperature schedule for nitridation of silicon compact on the basis of silicon and nitrogen reaction kinetics
Rakshit, J
Das, PK
BULLETIN OF MATERIALS SCIENCE, 2000, 23 (04) : 249 - 253
[32] Effects of water vapour on the high temperature nitridation of chromium
Michalik, M.
Tobing, S. L.
Haensel, M.
Shemet, V.
Quadakkers, W. J.
Young, D. J.
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2014, 65 (03): : 260 - 266
[33] Reaction kinetics and pathways for phytol in high-temperature water
Changi, Shujauddin
Brown, Tylisha M.
Savage, Phillip E.
CHEMICAL ENGINEERING JOURNAL, 2012, 189 : 336 - 345
[34] Role of nitrogen in the high-temperature oxidation of titanium alloys
Valenza, Thomas C.
Weber, Peter K.
Marquis, Emmanuelle A.
CORROSION SCIENCE, 2024, 235
[35] Reaction pathways and kinetics of cholesterol in high-temperature water
Hietala, David C.
Savage, Phillip E.
CHEMICAL ENGINEERING JOURNAL, 2015, 265 : 129 - 137
[36] Synthesis of zirconium diboride–zirconium nitride composite powders by self-propagating high-temperature synthesis
H. E. Çamurlu
F. Maglia
Journal of Materials Science, 2007, 42 : 10288 - 10295
[37] Investigation of the high-temperature properties of zirconium nitride by impulse current heating method
Onufriev, S. V.
Kondratiev, A. M.
Savvatimskiy, A. I.
Val'yano, G. E.
Muboyajan, S. A.
HIGH TEMPERATURE, 2015, 53 (03) : 455 - 457
[38] Investigation of the high-temperature properties of zirconium nitride by impulse current heating method
S. V. Onufriev
A. M. Kondratiev
A. I. Savvatimskiy
G. E. Val’yano
S. A. Muboyajan
High Temperature, 2015, 53 : 455 - 457
[39] High-pressure high-temperature behavior of nitrogen-doped zirconia
Locherer, T.
Frost, D.
Fuess, H.
JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (11) : 2983 - 2988
[40] Experimental and numerical study of the effects of a nanocrystallisation treatment on high-temperature oxidation of a zirconium alloy
Panicaud, B.
Retraint, D.
Grosseau-Poussard, J. -L.
Li, L.
Guerain, M.
Goudeau, P.
Tamura, N.
Kunz, M.
CORROSION SCIENCE, 2012, 60 : 224 - 230

← 1 2 3 4 5 →