Self-assembly of 1,4-cis-polybutadiene and an aromatic host to fabricate nanostructured crystals by CH•••π interactions

被引:26
作者
Bracco, Silvia [1 ]
Comotti, Angiolina [1 ]
Valsesia, Patrizia [1 ]
Beretta, Mario [1 ]
Sozzani, Piero [1 ]
机构
[1] Univ Milano Bicocca, Dept Mat Sci, Milan, Italy
来源
CRYSTENGCOMM | 2010年 / 12卷 / 08期
关键词
SOLID-STATE NMR; MAS NMR; INCLUSION; POLYMER; NANOCOMPOSITES; NANOCHANNELS; PERHYDROTRIPHENYLENE; CONFORMATION; SPECTROSCOPY; DYNAMICS;
D O I
10.1039/c002931a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Self-assembled supramolecular crystals fabricated by solvent-free mechanochemical treatments of a crystalline host and a rubbery polymer are stabilized by cooperative CH center dot center dot center dot pi interactions as revealed by H-1 fast-MAS and 2D solid state NMR.
引用
收藏
页码:2318 / 2321
页数:4
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