Kinetic comparison of isomeric oligo(ethylene oxide) (meth)acrylates: Aqueous polymerization of oligo(ethylene oxide) methyl ether methacrylate and methyl 2-(oligo(ethylene oxide) methyl ether)acrylate macromonomers

被引：0
作者：
Martinez, Michael R. [1 ]
Dworakowska, Sylwia [1 ,2 ]
Gorczynski, Adam [1 ,3 ]
Szczepaniak, Grzegorz [1 ]
Bossa, Ferdinando De Luca [1 ]
Matyjaszewski, Krzysztof [1 ]
机构：
[1] Carnegie Mellon Univ, Ctr Macromol Engn, Dept Chem, 4400 Fifth Ave, Pittsburgh, PA 15213 USA
[2] Cracow Univ Technol, Fac Chem Engn & Technol, Dept Biotechnol & Renewable Mat, Krakow, Poland
[3] Adam Mickiewicz Univ, Fac Chem, Poznan, Poland
来源：
JOURNAL OF POLYMER SCIENCE | 2022年 / 60卷 / 12期
基金：
美国安德鲁·梅隆基金会; 美国国家科学基金会;
关键词：
bottlebrushes; kinetics; macromonomer; methacrylate; PET-RAFT; FREE-RADICAL POLYMERIZATION; MOLECULAR BRUSHES; RAFT POLYMERIZATION; CHAIN TRANSFER; SOLVENT-FREE; COPOLYMERS; BEHAVIOR; ATRP; DISPROPORTIONATION; COMB;
D O I：
10.1002/pol.20220086
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The photoinduced energy/electron transfer-reversible addition-fragmentation chain transfer (PET-RAFT) polymerizations of oligo(ethylene oxide) monomethyl ether methacrylate (OEOMA, also known as poly[ethylene glycol] methyl ether methacrylate, PEGMA) and isomeric methyl 2-(oligo(ethylene oxide) methyl ether)acrylate (2OEOAM) macromonomers with OEO average degree of polymerization of 22 or 45 were conducted in aqueous media to provide insight into the effect of monomer structure on grafting-through RAFT of 1,1-disubstituted acrylic macromonomers. The polymerizations of all four monomers reached nearly quantitative conversion. The longer macromonomers polymerized faster than the shorter ones within the same monomer class. The OEO side chain at the alpha (i.e., 2-) position of isomeric acrylates significantly slowed RAFT polymerization in comparison with OEO ester side chain of methacrylates.
引用
收藏
页码：1887 / 1898
页数：12
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