Development of W-Reinforced Zr-Based Metallic Glass

被引:5
作者
Terajima, Takeshi [1 ]
Nakata, Kazuhiro [1 ]
Kimura, Hisamichi [2 ]
Inoue, Akihisa
机构
[1] Osaka Univ, Joining & Welding Res Inst, Ibaraki 5670876, Japan
[2] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan
关键词
metallic glass; composite; tungsten; plastic deformation; thermal expansion coefficient; MECHANICAL-PROPERTIES; MATRIX COMPOSITES; PARTICLES; BEHAVIOR;
D O I
10.2320/jinstmet.74.85
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
In order to improve the mechanical properties of Zr55Al10Ni5Cu30 metallic glass, tungsten-reinforced Zr55Al10Ni5Cu30 was developed. Tungsten particles with a diameter phi = 100 mu m were uniformly distributed into the matrix, exhibiting good wettability with the Zr55Al10Ni5Cu30 metallic glass matrix. Due to the extremely high melting temperature of tungsten, the tungsten particles coexisted with amorphous Zr55Al10Ni5Cu30, although a reaction layer of ZrW2 and a crystallized matrix formed to a certain extent depending on the sample. Nevertheless, the total amount of crystallization in both the matrix and the reaction phases remained small. As the volume fraction of W was increased front 0 to 8.7%, the compressive plastic strain increased from 0 to 1.3%, and the compressive fracture strength increased front 1480 MPa to 1870 MPa. The coefficient of thermal expansion of monolithic Zr55Al10N15Cu30 decreased from 10.4 x 10(-6)/K to 8.2 x 10(-6)/ K in the case of the composite containing 30% W powder.
引用
收藏
页码:85 / 88
页数:4
相关论文
共 12 条
[1]   Improved mechanical behavior of Cu-Ti-based bulk metallic glass by in situ formation of nanoscale precipitates [J].
Calin, M ;
Eckert, J ;
Schultz, L .
SCRIPTA MATERIALIA, 2003, 48 (06) :653-658
[2]   Work-hardenable ductile bulk metallic glass [J].
Das, J ;
Tang, MB ;
Kim, KB ;
Theissmann, R ;
Baier, F ;
Wang, WH ;
Eckert, J .
PHYSICAL REVIEW LETTERS, 2005, 94 (20)
[3]   Synthesis and mechanical properties of Cu-based bulk metallic glass composites containing in-situ TiC particles [J].
Fu, HM ;
Zhang, HF ;
Wang, H ;
Zhang, QS ;
Hu, ZQ .
SCRIPTA MATERIALIA, 2005, 52 (07) :669-673
[4]   Synthesis and mechanical properties of Zr55Al10Ni5Cu30 bulk glass composites containing ZrC particles formed by the in-situ reaction [J].
Hirano, T ;
Kato, H ;
Matsuo, A ;
Kawamura, Y ;
Inoue, A .
MATERIALS TRANSACTIONS JIM, 2000, 41 (11) :1454-1459
[5]   Synthesis and mechanical properties of bulk amorphous Zr-Al-Ni-Cu alloys containing ZrC particles [J].
Kato, H ;
Inoue, A .
MATERIALS TRANSACTIONS JIM, 1997, 38 (09) :793-800
[6]  
Kim K, 2006, APPL PHYS LETT, V88, DOI [10.1063/1.2199970, 10.1063/1.2171472]
[7]   Synthesis and characterization of particulate reinforced Mg-based bulk metallic glass composites [J].
Li, Jieqiong ;
Wang, Lu ;
Zhang, Haifeng ;
Hu, Zhuangqi ;
Cai, Hongnian .
MATERIALS LETTERS, 2007, 61 (11-12) :2217-2221
[8]   Enhanced plasticity in Mg-based bulk metallic glass composite reinforced with ductile Nb particles [J].
Pan, D. G. ;
Zhang, H. F. ;
Wang, A. M. ;
Hu, Z. Q. .
APPLIED PHYSICS LETTERS, 2006, 89 (26)
[9]   Nanoscale multistep shear band formation by deformation-induced nanocrystallization in Zr-Al-Ni-Pd bulk metallic glass [J].
Saida, J ;
Setyawan, ADH ;
Kato, H ;
Inoue, A .
APPLIED PHYSICS LETTERS, 2005, 87 (15) :1-3
[10]   Formation, thermal stability and deformation behavior of graphite-flakes reinforced Cu-based bulk metallic glass matrix composites [J].
Sun, Y. F. ;
Shek, C. H. ;
Guan, S. K. ;
Wei, B. C. ;
Geng, J. Y. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 435 :132-138