Rhodaelectro-catalyzed chemo-divergent C-H activations with alkylidenecyclopropanes for selective cyclopropylations

被引：17

作者：

Shen, Zhigao ^{[1
,2
]}

Maksso, Isaac ^{[1
,2
]}

Kuniyil, Rositha ^{[1
,2
]}

Rogge, Torben ^{[1
,2
]}

Ackermann, Lutz ^{[1
]}

机构：

[1] Georg August Univ Gottingen, Inst Organs & Biomol Chem, Tammannstr 2, D-37077 Gottingen, Germany

[2] Georg August Univ Gottingen, Wohler Res Inst Sustainable Chem, Tammannstr 2, D-37077 Gottingen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 30期

关键词：

CARBON-CARBON BONDS; ORGANIC ELECTROSYNTHESIS; EFFICIENT TOOL; ELECTROCHEMISTRY; FUNCTIONALIZATION; CLEAVAGE; METALLAELECTROCATALYSIS; OLEFINS;

D O I：

10.1039/d0cc08123j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report on selectivity control in C-H activations with alkylidenecyclopropanes (ACPs) for the chemo-selective assembly of cyclopropanes or dienes. Thus, unprecedented rhodaelectro-catalyzed C-H activations were realized with diversely decorated ACPs with a wide substrate scope and electricity as the sole oxidant.

引用

页码：3668 / 3671

页数：4

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