Reliable and Diverse Synthesis of Aryl Azides through Copper-Catalyzed Coupling of Boronic Acids or Esters with TMSN3

被引：81

作者：

Li, Yu ^{[1
,2
]}

Gao, Lian-Xun ^{[1
]}

Han, Fu-She ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Jilin, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 27期

关键词：

aryl azides; boronic acids; boronic esters; copper; cross-coupling; HUISGEN 1,3-DIPOLAR CYCLOADDITION; CLICK CHEMISTRY APPROACH; TETRAZOLE FORMATION; AROMATIC-AMINES; REACTIVITY; AZIRIDINES; CONVERSION; COMPLEXES; NITRILES; CYANIDES;

D O I：

10.1002/chem.201000971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Aryl azide formation: The copper-catalyzed coupling reaction of boronic esters and acids with TMSN3 have been presented as a highly efficient, simple, broadly applicable, and less hazardous methodology for the practi cal synthesis of aryl azides with structural diversity (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7969 / 7972

页数：4

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