Visible light induced photopolymerization: speeding up the rate of polymerization by using co-initiators in dye/amine photoinitiating systems

被引：81
作者：
Grotzinger, C [1 ]
Burget, D [1 ]
Jacques, P [1 ]
Fouassier, JP [1 ]
机构：
[1] Ecole Natl Super Chim, Dept Photochim Gen, UMR 7525, CNRS, F-68093 Mulhouse, France
来源：
POLYMER | 2003年 / 44卷 / 13期
关键词：
photoinitiator; photopolymerization; dye;
D O I：
10.1016/S0032-3861(03)00286-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The activity of six newly designed three-component systems (containing a dye, an amine and a triazine derivative) for the initiation of the photopolymerization of multifunctional acrylates under visible light has been evaluated. The selection of the dyes was based on thermodynamic considerations. A discussion of the photochemical reactivity of these systems reveals the role played by thermodynamics and outlines different aspects concerned with kinetics. (C) 2003 Elsevier Science Ltd. All rights reserved.
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收藏
页码：3671 / 3677
页数：7
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