When gold meets chiral Bronsted acid catalysts: extending the boundaries of enantioselective gold catalysis

被引：100

作者：

Inamdar, Suleman M. ^{[1
]}

Konala, Ashok ^{[1
]}

Patil, Nitin T. ^{[1
]}

机构：

[1] Natl Chem Lab, CSIR, Div Organ Chem, Pune 411008, Maharashtra, India

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 96期

关键词：

ASYMMETRIC ALDOL REACTION; RELAY CATALYSIS; TRANSFER HYDROGENATION; PHOSPHORIC-ACID; DIAMINOCARBENE COMPLEXES; PLATINUM CATALYSIS; TRANSITION-METAL; CYCLIC AMINALS; HYDROAMINATION; CYCLIZATION;

D O I：

10.1039/c4cc04633a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review describes the development in the use of Au(I)/Bronsted acid binary catalytic systems to enable an enantioselective transformation in one-pot that cannot be achieved by gold catalysts alone. The examples discussed herein are promising since apart from using chiral ligands there exists a possibility of using chiral Bronsted acids. Clearly, the horizon for enantioselective gold catalysis has been expanded as more options to make the gold-catalyzed reactions enantioselective have become available.

引用

页码：15124 / 15135

页数：12

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