Transparent Metal-Organic Framework/Polymer Mixed Matrix Membranes as Water Vapor Barriers

被引：30

作者：

Bae, Youn Jue ^{[1
,3
]}

Cho, Eun Seon ^{[3
]}

Qu, Fen ^{[3
]}

Sun, Daniel T.

Williams, Teresa E. ^{[2
,3
]}

Urban, Jeffrey J. ^{[3
]}

Queen, Wendy L. ^{[4
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Grad Grp Appl Sci & Technol, Berkeley, CA 94720 USA

[3] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Mol Foundry, Berkeley, CA 94720 USA

[4] EPFL, Inst Sci & Ingn Chim, CH-1051 Sion, Switzerland

来源：

ACS APPLIED MATERIALS & INTERFACES | 2016年 / 8卷 / 16期

基金：

瑞士国家科学基金会;

关键词：

metal-organic framework; postsynthetic modification; water vapor transmission rate; mixed-matrix membrane gas barrier; encapsulant; MODULATED SYNTHESIS; COATINGS;

D O I：

10.1021/acsami.6b01299

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Preventing the permeation of reactive molecules into electronic devices or photovoltaic modules is of great importance to ensure their life span and reliability. This work is focused on the formation of highly functioning barrier films based on nanocrystals (NCs) of a water-scavenging metal organic framework (MOP) and a hydrophobic cyclic olefin copolymer (COC) to overcome the current limitations. Water vapor transmission rates (WVTR) of the films reveal a 10-fold enhancement in the WVTR compared to the substrate while maintaining outstanding transparency over most of the visible and solar spectrum, a necessary condition for integration with optoelectronic devices.

引用

页码：10098 / 10103

页数：6

共 50 条

[1] Metal Organic Framework Based Polymer Mixed Matrix Membranes: Review on Applications in Water Purification
Elrasheedy, Asmaa
Nady, Norhan
Bassyouni, Mohamed
El-Shazly, Ahmed
MEMBRANES, 2019, 9 (07)
[2] Recent developments in Metal-organic framework-based mixed matrix membranes for hydrogen separation
Wu, Qian
He, Xinping
Cui, Chenyi
Qi, Baojin
Wei, Jinjia
SEPARATION AND PURIFICATION TECHNOLOGY, 2025, 354
[3] Influence of casting solvents on sedimentation and performance in metal-organic framework mixed-matrix membranes
Chang, Yi-Wei
Chang, Bor Kae
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2018, 89 : 224 - 233
[4] Metal organic framework mixed matrix membranes for gas separations
Adams, Ryan
Carson, Cantwell
Ward, Jason
Tannenbaum, Rina
Koros, William
MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 131 (1-3) : 13 - 20
[5] Metal confined in metal-organic framework-based mixed matrix membranes for efficient butadiene recognition separation
Cen, Xixi
Sun, Yuxiu
Yu, Caijiao
Qiao, Zhihua
Zhong, Chongli
AGGREGATE, 2023, 4 (05):
[6] Metal-organic framework membranes for wastewater treatment and water regeneration
Li, Juan
Wang, Hou
Yuan, Xingzhong
Zhang, Jingjing
Chew, Jia Wei
COORDINATION CHEMISTRY REVIEWS, 2020, 404
[7] Review of Synthesis and Separation Application of Metal-Organic Framework-Based Mixed-Matrix Membranes
Wang, Lu
Huang, Jingzhe
Li, Zonghao
Han, Zhiwu
Fan, Jianhua
POLYMERS, 2023, 15 (08)
[8] Mixed matrix membranes incorporated with polydopamine-coated metal-organic framework for dehydration of ethylene glycol by pervaporation
Zhang, Weixin
Ying, Yunpan
Ma, Jing
Guo, Xiangyu
Huang, Hongliang
Liu, Dahuan
Zhong, Chongli
JOURNAL OF MEMBRANE SCIENCE, 2017, 527 : 8 - 17
[9] Water Desalination with Two-Dimensional Metal-Organic Framework Membranes
Cao, Zhonglin
Liu, Vincent
Farimani, Amir Barati
NANO LETTERS, 2019, 19 (12) : 8638 - 8643
[10] Scalable Fabrications of Mixed-Matrix Membranes via Polymer Modification-Enabled In Situ Metal-Organic Framework Formation for Gas Separation: A Review
Park, Sunghwan
Lee, Young-Sei
APPLIED CHEMISTRY FOR ENGINEERING, 2023, 34 (03): : 213 - 220

← 1 2 3 4 5 →