Heteroatom-doped porous carbon from methyl orange dye wastewater for oxygen reduction

Banana peel-derived porous carbon (BPPC) was prepared from banana peel and used as an adsorbent for methyl orange (MO) wastewater removal. BPPC-MO50 is a N,S-doped BPPC obtained via secondary carbonization. The BPPC-MO50 exhibited a high specific surface area of 1774.3 m(2)/g. Heteroatom-doped porous carbon (PC) was successfully synthesized from the BPPC absorbed MO at high temperature and used for oxygen reduction. The BPPC-MO50 displayed the highest ORR onset potential among all carbon-based electrocatalysts, i.e., 0.93 V vs. reversible hydrogen electrode (RHE). This is the first report to describe porous carbon-activated materials from agriculture and forestry waste that is used for adsorption of dyes from wastewater via an enhanced heteroatom (N,S) content. These results may contribute to the sustainable development of dye wastewater treatment by transforming saturated PC into an effective material and has potential applications in fuel cells or as energy sources. (C) 2018, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V.