Metal-metal (hydr)oxide heterostructures for electrocatalysis of hydrogen electrode reactions

被引：15
作者：
Oshchepkov, Alexandr G. [1 ]
Bonnefont, Antoine [2 ]
Savinova, Elena R. [3 ]
机构：
[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[2] Univ Strasbourg, Inst Chim Strasbourg, UMR 7177 CNRS, F-67070 Strasbourg, France
[3] Univ Strasbourg, Inst Chim & Proc Energie Environm & Sante, UMR 7515 CNRS, F-67087 Strasbourg, France
来源：
CURRENT OPINION IN ELECTROCHEMISTRY | 2021年 / 26卷
关键词：
Hydrogen electrode reactions in alkaline electrolytes; pH effect; Metal/metal oxide heterostructures hydrogen bonding; Interfacial water structure; EVOLUTION REACTION; OXIDATION REACTION; NICKEL HYDROXIDE; WATER; SURFACE; KINETICS; CATALYST; NI; NANOSTRUCTURES; INSIGHTS;
D O I：
10.1016/j.coelec.2020.100667
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Metal/metal (hydr)oxide heterostructures have been proposed as an efficient means to enhance the kinetics of hydrogen electrode reactions (the hydrogen evolution and the hydrogen oxidation reaction) on Pt, Ni, and other electrodes in the alkaline medium. However, the reasons for the faster electrode kinetics are still not fully understood. By considering two electrode materials, namely Pt and Ni, widely studied in hydrogen electrode reactions in alkaline media, this review brings to light differences in their pH-dependent behavior and likely different genesis of the enhancement in the presence of 3d transition metal oxides.
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页数：13
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